Ba3(VO4)2crystal　with　dimension　φ22　mm　×　50　mm　has　been　grown　by　the　Czochralski　method.　The　spontaneous　Raman　spectra　of　Ba3(VO4)2crystal　excited　in　different　geometries　were　measured　at　room　temperature.　In　addition,　the　stimulated　Raman　scattering　of　532　nm,　25　ps　pulse　was　observed　in　the　crystal　sample,　the　third　Stokes　line　(625.5　nm)　and　the　first　anti-Stokes　line　(506.8　nm)　were　observed,　and　the　steady-state　gain　coefficient　was　calculated.