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author:

Zhang, Ying-Ying (Zhang, Ying-Ying.) [1] | Liu, Shi-Xiong (Liu, Shi-Xiong.) [2]

Indexed by:

EI

Abstract:

The CeIII ion in the title complex, [Ce(NO3)3(C13H12N4O)2], is 12-coordinated by six chelating nitrate O atoms and six donors (2 O and 4 N atoms) of two N'-[1-(2-pyrid-yl)ethyl-idene]isonicotinohydrazide ligands, exhibiting a bicapped penta-gonal-anti-prism-type coordination geometry. The title complex possesses C 2 point symmetry and is located on a twofold crystallographic axis. Each mol-ecule is linked with four surrounding mol-ecules by four N - HN hydrogen bonds, resulting in an extended two-dimensional layer parallel to the ab plane, while π-π inter-actions between pyridine rings from neighboring complex mol-ecules connect the two-dimensional layers into a three-dimensional cerium-organic supra-molecular structure. © 2009 International Union of Crystallography.

Keyword:

Cerium compounds Coordination reactions Hydrogen bonds Molecular structure

Community:

  • [ 1 ] [Zhang, Ying-Ying]Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China
  • [ 2 ] [Liu, Shi-Xiong]Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China

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Source :

Acta Crystallographica Section C: Crystal Structure Communications

ISSN: 0108-2701

Year: 2009

Issue: 7

Volume: 65

Page: m269-m272

0 . 7 8 2

JCR@2009

0 . 3 2 6

JCR@2014

JCR Journal Grade:3

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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