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Mesoporous graphitic$ carbon nitride (mpg-CN) was loaded with WS2 via an impregnation-sulfidation approach. The resultant surface heterojunctions between WS2 and mpg-CN were evidently confirmed with transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS). Photocatalytic H2 production on WS2/mpg-CN under visible light (λ>420nm) shows that WS2 plays an important role in catalyzing H2 production. The rate of hydrogen evolution reaches an optimum when the loading amount of WS2 is about 0.3at.%. Combined with the physicochemical and electrocatalytic properties of WS2/mpg-CN, it can be concluded that the enhanced photocatalytic H2 production activity on WS2/mpg-CN is mainly attributed to the thin layered junctions formed between WS2 and mpg-CN and the great performance of WS2 as a cocatalyst in H2 evolution reaction. © 2014 Elsevier B.V.
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Applied Catalysis B: Environmental
ISSN: 0926-3373
Year: 2014
Volume: 156-157
Page: 122-127
7 . 4 3 5
JCR@2014
2 0 . 3 0 0
JCR@2023
ESI HC Threshold:268
JCR Journal Grade:1
CAS Journal Grade:1
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