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author:

Cai, Jindi (Cai, Jindi.) [1] | Huang, Yiyin (Huang, Yiyin.) [2] | Huang, Binbin (Huang, Binbin.) [3] | Zheng, Shiying (Zheng, Shiying.) [4] | Guo, Yonglang (Guo, Yonglang.) [5]

Indexed by:

EI

Abstract:

Pt nanoparticles deposited on manganese oxide-carbon nanotubes (Pt/MnO x-CNTs) are prepared by a microwave-assisted polyol method. Their structure characterizations are carried out by Fourier transform infrared spectrometry (FTIR), thermogravimetric analysis (TGA), X-ray diffraction (XRD), transmission electron microscope (TEM) and X-ray photoelectron spectroscopy (XPS) measurements, indicating that MnOx nanoparticles cover the surface of CNTs and then Pt nanoparticles are uniformly dispersed on MnO x-CNTs with the average particle size of about 2.2 nm. Ethanol oxidation peak current on Pt/MnOx-CNTs (1141.4 mA mg-1 Pt) is 1.82 times higher than that on Pt/CNTs (626.4 mA mg-1 Pt) and 1.28 times higher than that on PtRu/C (JM) (888.6 mA mg-1 Pt). The Pt/MnOx-CNT catalyst presents not only excellent electrocatalytic activity and very high stability for ethanol oxidation, but also high tolerance to the poisonous carbonaceous intermediates generated during ethanol oxidation compared to Pt/CNT catalyst. This is attributed to the excellent proton conductivity of MnOx and the synergistic effect between Pt and MnOx. The optimum mass ratio of MnOx to CNTs is 1:1 in the Pt/MnOx-CNT catalysts. Copyright © 2013, Hydrogen Energy Publications, LLC.

Keyword:

Carbon nanotubes Catalyst activity Ethanol Fourier transform infrared spectroscopy Fuel cells Manganese oxide Metal nanoparticles Nanocatalysts Oxidation Oxides Particle size Particle size analysis Reaction intermediates Thermogravimetric analysis Transmission electron microscopy X ray photoelectron spectroscopy

Community:

  • [ 1 ] [Cai, Jindi]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108, China
  • [ 2 ] [Huang, Yiyin]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108, China
  • [ 3 ] [Huang, Binbin]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108, China
  • [ 4 ] [Zheng, Shiying]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108, China
  • [ 5 ] [Guo, Yonglang]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108, China

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Source :

International Journal of Hydrogen Energy

ISSN: 0360-3199

Year: 2014

Issue: 2

Volume: 39

Page: 798-807

3 . 3 1 3

JCR@2014

8 . 1 0 0

JCR@2023

ESI HC Threshold:184

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 46

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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