• Complex
  • Title
  • Keyword
  • Abstract
  • Scholars
  • Journal
  • ISSN
  • Conference
成果搜索

author:

Chen, Jianfu (Chen, Jianfu.) [1] | Zhang, Weiying (Zhang, Weiying.) [2] | Li, Xiao (Li, Xiao.) [3]

Indexed by:

EI

Abstract:

A novel konjac glucomannan-acrylic acid superabsorbent (KGMP) was prepared by the solution polymerization of partially neutralized acrylic acid (AA) onto konjac glucomannan (KGM) using potassium persulfate (KPS) as a free radical initiator and trimethylolpropane trimethacrylate (TPTA) as a crosslinking agent. Effects of the content of TPTA on the water absorption in buffer solutions of different pH were investigated. The results showed that the swelling ratio exhibited the largest value at pH 7.4 due to electrical interaction. There was an appropriate content of TPTA in the KGMP that made the swelling ratio reach its maximum. Swelling kinetics of the KGMP at pH 7.4 was also studied. The swelling processes of the polymers can be fitted to the first-order reaction kinetics. The structure, morphology and thermal stability of KGMP were further characterized using Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), thermogravimetric analysis (TGA) and scanning electron microscopy (SEM), using KGM as reference. Results indicated that a successful graft polymerization reaction and excellent miscibility occurred between KGM and AA and the content of TPTA affected the orderliness of KGMP. This journal is © The Royal Society of Chemistry 2015.

Keyword:

Ascorbic acid Carboxylic acids Fourier transform infrared spectroscopy Free radical polymerization Free radicals Potassium compounds Reaction kinetics Scanning electron microscopy Thermodynamic stability Thermogravimetric analysis Water absorption

Community:

  • [ 1 ] [Chen, Jianfu]School of Chemical Engineering, Fuzhou University, Fuzhou Fujian; 350108, China
  • [ 2 ] [Chen, Jianfu]Department of Food and Biology Engineering, Zhangzhou Institute of Technology, Zhangzhou Fujian; 363000, China
  • [ 3 ] [Zhang, Weiying]School of Chemical Engineering, Fuzhou University, Fuzhou Fujian; 350108, China
  • [ 4 ] [Li, Xiao]School of Chemical Engineering, Fuzhou University, Fuzhou Fujian; 350108, China

Reprint 's Address:

  • [li, xiao]school of chemical engineering, fuzhou university, fuzhou fujian; 350108, china

Show more details

Related Keywords:

Source :

RSC Advances

Year: 2015

Issue: 48

Volume: 5

Page: 38417-38423

3 . 2 8 9

JCR@2015

3 . 9 0 0

JCR@2023

ESI HC Threshold:265

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 17

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

Affiliated Colleges:

Online/Total:182/9526464
Address:FZU Library(No.2 Xuyuan Road, Fuzhou, Fujian, PRC Post Code:350116) Contact Us:0591-22865326
Copyright:FZU Library Technical Support:Beijing Aegean Software Co., Ltd. 闽ICP备05005463号-1