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author:

Chen, Jianfu (Chen, Jianfu.) [1] | Zhang, Weiying (Zhang, Weiying.) [2] (Scholars:张卫英) | Li, Xiao (Li, Xiao.) [3] (Scholars:李晓)

Indexed by:

EI Scopus SCIE

Abstract:

A novel konjac glucomannan-acrylic acid superabsorbent (KGMP) was prepared by the solution polymerization of partially neutralized acrylic acid (AA) onto konjac glucomannan (KGM) using potassium persulfate (KPS) as a free radical initiator and trimethylolpropane trimethacrylate (TPTA) as a crosslinking agent. Effects of the content of TPTA on the water absorption in buffer solutions of different pH were investigated. The results showed that the swelling ratio exhibited the largest value at pH 7.4 due to electrical interaction. There was an appropriate content of TPTA in the KGMP that made the swelling ratio reach its maximum. Swelling kinetics of the KGMP at pH 7.4 was also studied. The swelling processes of the polymers can be fitted to the first-order reaction kinetics. The structure, morphology and thermal stability of KGMP were further characterized using Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), thermogravimetric analysis (TGA) and scanning electron microscopy (SEM), using KGM as reference. Results indicated that a successful graft polymerization reaction and excellent miscibility occurred between KGM and AA and the content of TPTA affected the orderliness of KGMP.

Keyword:

Community:

  • [ 1 ] [Chen, Jianfu]Fuzhou Univ, Sch Chem Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 2 ] [Zhang, Weiying]Fuzhou Univ, Sch Chem Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 3 ] [Li, Xiao]Fuzhou Univ, Sch Chem Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 4 ] [Chen, Jianfu]Zhangzhou Inst Technol, Dept Food & Biol Engn, Fujian 363000, Peoples R China

Reprint 's Address:

  • 李晓

    [Li, Xiao]Fuzhou Univ, Sch Chem Engn, Fuzhou 350108, Fujian, Peoples R China

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RSC ADVANCES

ISSN: 2046-2069

Year: 2015

Issue: 48

Volume: 5

Page: 38417-38423

3 . 2 8 9

JCR@2015

3 . 9 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:265

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 17

SCOPUS Cited Count: 17

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 4

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