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author:

Chen, Qidi (Chen, Qidi.) [1] | Cai, Daoping (Cai, Daoping.) [2] | Zhan, Hongbing (Zhan, Hongbing.) [3]

Indexed by:

EI

Abstract:

Binary metal sulfides have been considered as promising electrode materials for supercapacitors with excellent performance. Herein, we demonstrate a simple two-step hydrothermal method to grow the interconnected Co9S8/NiCo2S4 nanosheet arrays (denoted as Ni-Co sulfide NSAs) on nickel foam with robust adhesion for high performance supercapacitors. Remarkably, the as-synthesized Ni-Co sulfide binder-free electrode exhibits an ultrahigh areal capacitance of 7.4 F cm−2 for supercapacitors, which is about five times higher than 1.5 F cm−2 of the Ni-Co oxide electrode at the current density of 5 mA cm−2. The Ni-Co sulfide binder-free electrode also exhibits a good cycling stability, which still displays a high capacitance retention of 90.7% after 2000 cycles even at a high current density of 40 mA cm−2. The good electrochemical performance could be ascribed to the high electrical conductivity and porous nanosheet structure of the Ni-Co sulfide nanosheets, as well as the robust adhesion with the current collector. These electrochemical results suggest that such Ni-Co sulfide NSA binder-free electrode might hold some potential for electrochemical energy applications. © 2017 Elsevier B.V.

Keyword:

Adhesion Binary alloys Capacitance Cobalt compounds Electrochemical electrodes Nanosheets Nickel oxide Sulfur compounds Supercapacitor

Community:

  • [ 1 ] [Chen, Qidi]College of Materials Science and Engineering, Fuzhou University, Fuzhou; Fujian; 350116, China
  • [ 2 ] [Cai, Daoping]College of Materials Science and Engineering, Fuzhou University, Fuzhou; Fujian; 350116, China
  • [ 3 ] [Zhan, Hongbing]College of Materials Science and Engineering, Fuzhou University, Fuzhou; Fujian; 350116, China
  • [ 4 ] [Zhan, Hongbing]Key Laboratory of Eco-materials Advanced Technology, Fuzhou University, Fujian Province, China

Reprint 's Address:

  • [zhan, hongbing]college of materials science and engineering, fuzhou university, fuzhou; fujian; 350116, china;;[zhan, hongbing]key laboratory of eco-materials advanced technology, fuzhou university, fujian province, china

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Source :

Journal of Alloys and Compounds

ISSN: 0925-8388

Year: 2017

Volume: 721

Page: 205-212

3 . 7 7 9

JCR@2017

5 . 8 0 0

JCR@2023

ESI HC Threshold:306

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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