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Abstract:
Er,Eu:YAlO3 (abbr. as Er,Eu:YAP) crystal was grown by the Czochralski technique for the first time. Its absorption and fluorescence spectra as well as the fluorescence decay curves were measured and investigated. The spectral parameters including absorption cross-section and emission cross-section were calculated. It is found that the crystal has short lifetimes at 4I13/2 and 4I11/2 levels, large absorption cross-section at 974 nm and 790 nm, and large stimulated emission cross-section at 2704 nm. The co-dopant Eu3+ decreases the fluorescence lifetime of 4I11/2 level from 400 μs to 59.35 μs, and thus inhibits the self-termination effect of ~2.7 μm in some degree. We develop a theoretical model that simulates the laser characteristics of Er,Eu:YAP crystal numerically. Based on Er3+-Eu3+ energy level diagrams, the rate equation model was built and discussed. It was found that: when the pump rate increases gradually, the laser quantum efficiency reaches to its upper limit with a fixed value 2-p2, and this value is 1.35 for Er,Eu:YAP crystal. The results show that Er,Eu:YAP crystal is an excellent material candidate for ~2.7 μm laser. © 2018 Elsevier B.V.
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Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy
ISSN: 1386-1425
Year: 2018
Volume: 204
Page: 508-513
2 . 9 3 1
JCR@2018
4 . 3 0 0
JCR@2023
ESI HC Threshold:209
JCR Journal Grade:1
CAS Journal Grade:2
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ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 1
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