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author:

Zhang, Baotong (Zhang, Baotong.) [1] | Wang, Yan (Wang, Yan.) [2] | Zhang, Wei (Zhang, Wei.) [3] | Li, Jianfu (Li, Jianfu.) [4] | Zhu, Zhaojie (Zhu, Zhaojie.) [5] | You, Zhenyu (You, Zhenyu.) [6] | Tu, Chaoyang (Tu, Chaoyang.) [7]

Indexed by:

EI

Abstract:

Er,Eu:YAlO3 (abbr. as Er,Eu:YAP) crystal was grown by the Czochralski technique for the first time. Its absorption and fluorescence spectra as well as the fluorescence decay curves were measured and investigated. The spectral parameters including absorption cross-section and emission cross-section were calculated. It is found that the crystal has short lifetimes at 4I13/2 and 4I11/2 levels, large absorption cross-section at 974 nm and 790 nm, and large stimulated emission cross-section at 2704 nm. The co-dopant Eu3+ decreases the fluorescence lifetime of 4I11/2 level from 400 μs to 59.35 μs, and thus inhibits the self-termination effect of ~2.7 μm in some degree. We develop a theoretical model that simulates the laser characteristics of Er,Eu:YAP crystal numerically. Based on Er3+-Eu3+ energy level diagrams, the rate equation model was built and discussed. It was found that: when the pump rate increases gradually, the laser quantum efficiency reaches to its upper limit with a fixed value 2-p2, and this value is 1.35 for Er,Eu:YAP crystal. The results show that Er,Eu:YAP crystal is an excellent material candidate for ~2.7 μm laser. © 2018 Elsevier B.V.

Keyword:

Energy transfer Fluorescence Pumping (laser) Single crystals

Community:

  • [ 1 ] [Zhang, Baotong]Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou City; Fujian Province; 350002, China
  • [ 2 ] [Zhang, Baotong]College of Materials Science and Engineering, Fujian Normal University, Fuzhou City; Fujian Province; 350007, China
  • [ 3 ] [Wang, Yan]Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou City; Fujian Province; 350002, China
  • [ 4 ] [Zhang, Wei]Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou City; Fujian Province; 350002, China
  • [ 5 ] [Zhang, Wei]College of Chemistry, Fuzhou University, Fuzhou City; Fujian Province; 350116, China
  • [ 6 ] [Li, Jianfu]Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou City; Fujian Province; 350002, China
  • [ 7 ] [Zhu, Zhaojie]Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou City; Fujian Province; 350002, China
  • [ 8 ] [You, Zhenyu]Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou City; Fujian Province; 350002, China
  • [ 9 ] [Tu, Chaoyang]Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou City; Fujian Province; 350002, China

Reprint 's Address:

  • [wang, yan]key laboratory of optoelectronic materials chemistry and physics, fujian institute of research on the structure of matter, chinese academy of sciences, fuzhou city; fujian province; 350002, china

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Source :

Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy

ISSN: 1386-1425

Year: 2018

Volume: 204

Page: 508-513

2 . 9 3 1

JCR@2018

4 . 3 0 0

JCR@2023

ESI HC Threshold:209

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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