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author:

Zhang, Baotong (Zhang, Baotong.) [1] | Wang, Yan (Wang, Yan.) [2] | Zhang, Wei (Zhang, Wei.) [3] | Li, Jianfu (Li, Jianfu.) [4] | Zhu, Zhaojie (Zhu, Zhaojie.) [5] | You, Zhenyu (You, Zhenyu.) [6] | Tu, Chaoyang (Tu, Chaoyang.) [7]

Indexed by:

EI Scopus SCIE

Abstract:

Er,Eu:YAlO3 (abbr. as Er,Eu:YAP) crystal was grown by the Czochralski technique for the first time. Its absorption and fluorescence spectra as well as the fluorescence decay curves were measured and investigated. The spectral parameters including absorption cross-section and emission cross-section were calculated. It is found that the crystal has short lifetimes at I-4(13/2) and I-4(11/2) levels, large absorption cross-section at 974 nm and 790 nm, and large stimulated emission cross-section at 2704 nm. The co-dopant Eu3+ decreases the fluorescence lifetime of I-4(11/2) level from 400 mu s to 59.35 mu s, and thus inhibits the self-termination effect of similar to 2.7 pm in some degree. We develop a theoretical model that simulates the laser characteristics of Er,Eu:YAP crystal numerically. Based on Er3+-Eu3+ energy level diagrams, the rate equation model was built and discussed. It was found that: when the pump rate increases gradually, the laser quantum efficiency reaches to its upper limit with a fixed value 2-p(2), and this value is 135 for Er,Eu:YAP crystal. The results show that Er,Eu:YAP crystal is an excellent material candidate for similar to 2.7 mu m laser. (C) 2018 Elsevier B.V. All rights reserved.

Keyword:

Energy transfer Er3+ ions Er,Eu:YAP crystal Laser characterization simulation Spectroscopic properties

Community:

  • [ 1 ] [Zhang, Baotong]Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Optoelect Mat Chem & Phys, Fuzhou 350002, Fujian, Peoples R China
  • [ 2 ] [Wang, Yan]Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Optoelect Mat Chem & Phys, Fuzhou 350002, Fujian, Peoples R China
  • [ 3 ] [Zhang, Wei]Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Optoelect Mat Chem & Phys, Fuzhou 350002, Fujian, Peoples R China
  • [ 4 ] [Li, Jianfu]Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Optoelect Mat Chem & Phys, Fuzhou 350002, Fujian, Peoples R China
  • [ 5 ] [Zhu, Zhaojie]Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Optoelect Mat Chem & Phys, Fuzhou 350002, Fujian, Peoples R China
  • [ 6 ] [You, Zhenyu]Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Optoelect Mat Chem & Phys, Fuzhou 350002, Fujian, Peoples R China
  • [ 7 ] [Tu, Chaoyang]Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Optoelect Mat Chem & Phys, Fuzhou 350002, Fujian, Peoples R China
  • [ 8 ] [Zhang, Baotong]Fujian Normal Univ, Coll Mat Sci & Engn, Fuzhou 350007, Fujian, Peoples R China
  • [ 9 ] [Zhang, Wei]Fuzhou Univ, Coll Chem, Fuzhou 350116, Fujian, Peoples R China

Reprint 's Address:

  • [Wang, Yan]Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Optoelect Mat Chem & Phys, Fuzhou 350002, Fujian, Peoples R China

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Source :

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY

ISSN: 1386-1425

Year: 2018

Volume: 204

Page: 508-513

2 . 9 3 1

JCR@2018

4 . 3 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:209

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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