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author:

Pan, Bao (Pan, Bao.) [1] | Qin, Jiani (Qin, Jiani.) [2] | Wang, Xuxu (Wang, Xuxu.) [3] | Su, Wenyue (Su, Wenyue.) [4]

Indexed by:

EI

Abstract:

Root nodule-like LaPO4/CdS hierarchical heterostructures were constructed via in-situ growth of LaPO4 microspheres on the surface of CdS nanorods to remarkably enhance CO2 reduction under visible light. The self-assembly strategy allows intimate interfacial contact between LaPO4 and CdS, greatly facilitating the separation and transfer of photo-generated charge, which lifetime is increased from 18.6 ns to 48.5 ns. Benefiting from the synergistic effect of the enhanced CO2 adsorption and promoted visible light absorption, the optimized LaPO4/CdS photocatalyst shows excellent CO2 reduction performance with CO generation rate of 960 μmol⋅h−1⋅g−1, which is 3.9 times greater than the pure CdS nanorods. Moreover, considerable stability can be observed in LaPO4/CdS heterostructure photocatalysts. The current work provides a simple self-assembly approach to build 3D-1D semiconductor composites for artificial photosynthesis. © 2019 Elsevier B.V.

Keyword:

Artificial photosynthesis Cadmium sulfide Carbon dioxide Heterojunctions II-VI semiconductors Lanthanum compounds Light Light absorption Microspheres Nanorods Photocatalysis Photocatalytic activity Self assembly

Community:

  • [ 1 ] [Pan, Bao]State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fuzhou; 350116, China
  • [ 2 ] [Pan, Bao]Shaanxi Key Laboratory of Chemical Additives for Industry, College of Chemistry and Chemical Engineering, Shaanxi University of Science and Technology, Xi'an; 710021, China
  • [ 3 ] [Qin, Jiani]State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fuzhou; 350116, China
  • [ 4 ] [Wang, Xuxu]State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fuzhou; 350116, China
  • [ 5 ] [Su, Wenyue]State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fuzhou; 350116, China

Reprint 's Address:

  • [su, wenyue]state key laboratory of photocatalysis on energy and environment, fuzhou university, fuzhou; 350116, china

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Source :

Applied Surface Science

ISSN: 0169-4332

Year: 2020

Volume: 504

6 . 7 0 7

JCR@2020

6 . 3 0 0

JCR@2023

ESI HC Threshold:196

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 40

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 4

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