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author:

Li, Qiu (Li, Qiu.) [1] | Zhang, Wei-Ying (Zhang, Wei-Ying.) [2] (Scholars:张卫英) | Li, Xiao (Li, Xiao.) [3] (Scholars:李晓)

Indexed by:

CPCI-S EI Scopus

Abstract:

Molecularly imprinted polymers with specific recognition to salicylic acid (SA-MIPs) were prepared by oil-in-water emulsion polymerization using salicylic acid as template, acrylamide as functional monomer, and ethylene glycol dimethacrylate as crosslinker. The morphology and size distribution of the SA-MIPs were detected by SEM and photon cross correlation spectrometry. Equilibrium binding experiments and Scatchard analyses were carried out to investigate the selectivity of the SA-MIPs. The results show that the SA-MIPs exhibit a higher affinity and selectivity to salicylic acid than to m-hydroxybenzoic acid and sulfosalicylic acid. Two classes of binding sites were produced in the SA-MIPs and the equilibrium dissociation constants were estimated to be 2.03 and 9.97 mmol/L, respectively.

Keyword:

emulsion polymerization molecularly imprinted polymers recognition salicylic acid

Community:

  • [ 1 ] [Li, Qiu]Fuzhou Univ, Coll Chem & Chem Engn, Fuzhou 350002, Peoples R China
  • [ 2 ] [Zhang, Wei-Ying]Fuzhou Univ, Coll Chem & Chem Engn, Fuzhou 350002, Peoples R China
  • [ 3 ] [Li, Xiao]Fuzhou Univ, Coll Chem & Chem Engn, Fuzhou 350002, Peoples R China

Reprint 's Address:

  • 李晓

    [Li, Xiao]Fuzhou Univ, Coll Chem & Chem Engn, Fuzhou 350002, Peoples R China

Email:

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Source :

MACROMOLECULAR SYMPOSIA

ISSN: 1022-1360

Year: 2008

Volume: 261

Page: 91-96

Language: English

0 . 9 1 3

JCR@2005

Cited Count:

WoS CC Cited Count: 8

SCOPUS Cited Count: 9

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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