The　reaction　system　(NH4)(3)VS4/CuCl/PPh(3)/Et(4)NBr　afforded　a　series　of　[VS4-Cu-n]　clusters　with　various　core　configurations　in　the　solid　state　at　low　heating　temperature.　The　structural　regularity　of　[VS4-Cu-n]　clusters　and　the　influence　of　the　CuCL:(NH4)(3)VS4　ratio　as　well　as　that　of　reaction　temperature　and　time　on　the　formation　of　cluster　core　have　been　summarized.　The　reaction　mechanism　of　forming　V-Cu-S　clusters　has　also　been　explored.