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Abstract:
The reaction system (NH4)3VS4/CuCl/PPh3Et4NBr afforded a series of [VS4-Cun] clusters with various core configurations in the solid state at low heating temperature. The structural regularity of [VS4-Cun] clusters and the influence of the CuCl:(NH4)3VS4 ratio as well as that of reaction temperature and time on the formation of cluster core have been summarized. The reaction mechanism of forming V-Cu-S clusters has also been explored.
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Science in China, Series B: Chemistry
ISSN: 1006-9291
Year: 1996
Issue: 4
Volume: 39
Page: 433-438
1 . 1 9 9
JCR@2011
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ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 0
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