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author:

Gao, S (Gao, S.) [1] | Liu, SX (Liu, SX.) [2]

Indexed by:

SCIE PKU CSCD

Abstract:

The complex VO(L)(CH3O)(CH3OH) (H2L = salicylaldehyde benzoylhydrazone) was synthesize and characterized by elemental anlyasis, IR, UV, H-1 NMR, cyclic voltammetry measurements and X-ray diffraction, The crystal belongs to monoclinic system, space group P2(1)/c, with the crystal cell dimensions a = 0. 816 1(1) gm, b = 1. 694 6(2) nm, c =1. 223 2(1) nm, beta = 104. 274(9)degrees, V = 1. 639 4(3) nm(3), M-r = 368. 26, Z = 4. Two oxygen atoms and one nitrogen atom of the tridentate hydrazone ligand are coordinated to vanadium(V) atom, forming an equatorial plane, The vanadium atom approximates to a distorted octahedral coordination sphere. The redox potentials of the title complex in different solvents follow the order: CH2Cl2<CH3CN<DMF.

Keyword:

crystal structure hydrazone oxovanadium(V) complex redox properties

Community:

  • [ 1 ] Fuzhou Univ, Dept Chem, Fuzhou 350002, Peoples R China
  • [ 2 ] Heilongjiang Univ, Coll Chem & Chem Technol, Harbin 150080, Peoples R China

Reprint 's Address:

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    [Gao, S]Fuzhou Univ, Dept Chem, Fuzhou 350002, Peoples R China

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Source :

CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE

ISSN: 0251-0790

CN: 22-1131/O6

Year: 2000

Issue: 5

Volume: 21

Page: 671-674

0 . 5 9

JCR@2000

0 . 7 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:3

Cited Count:

WoS CC Cited Count: 8

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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