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author:

Yang, MX (Yang, MX.) [1] | Lin, S (Lin, S.) [2] | Chen, LJ (Chen, LJ.) [3] | Liu, SX (Liu, SX.) [4]

Indexed by:

Scopus SCIE PKU CSCD

Abstract:

The trinuclear nickel (11) complex Ni-3(C11H11N2O3)(2)(C5H5N)(4) was prepared by the reaction of Ni(OAc)(2) . 4H(2)O with N-butylsalicylhydrazide Schiff base ligand and characterized by X-ray crystallography. The crystal belongs to triclinic, M-1 = 930.91, space group P (1) over bar with cell parameters a = 9.8489(2) Angstrom, b = 12.3110(2) Angstrom, c = 18. 4035 (3) Angstrom, alpha = 71. 353 (2) beta = 76.638(2)degrees, gamma = 84. 815(2)degrees, V = 2056. 72(6) Angstrom(3), Z = 2, D = 1.503 g (.) cm(-3), mu(Mo Kalpha) = 1.417 mm F (000) = 964, R = 0.0317, wR = 0.0868. A total of 5393 independent reflections were collected, of which 4448 reflections with I greater than or equal to 2 a( I) were observed. There are two centrosymmetrical trinuclear molecules in a unit cell, each molecule exhibits a linear trinuclear metal arrangement with the Ni...Ni...Ni angle of 180degrees. The interatomic distances between the nickel atoms on the two sides are 9.2030(8) Angstrom and 9.1876 (9) Angstrom for the two molecules, respectively. The central nickel atom adopts an axially elongated octahedral geometry whereas the nickel atoms on the two sides have square-planar coordination environment.

Keyword:

crystal structure hydrazone nickel complex Schiff base

Community:

  • [ 1 ] Fujian Normal Univ, Dept Chem, Fuzhou 350007, Peoples R China
  • [ 2 ] Fuzhou Univ, Cent Lab, Fuzhou 350002, Peoples R China

Reprint 's Address:

  • [Lin, S]Fujian Normal Univ, Dept Chem, Fuzhou 350007, Peoples R China

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Source :

CHINESE JOURNAL OF INORGANIC CHEMISTRY

ISSN: 1001-4861

CN: 32-1185/O6

Year: 2003

Issue: 4

Volume: 19

Page: 433-436

0 . 5 3 5

JCR@2003

0 . 8 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:4

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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