Synthesis and Crystal Structure of Dibromo [1,1′ - Bis(diphenylphosphino)ferrocene]cadmium(II) - Details

author：

Wang, X.-L. (Wang, X.-L..) ^[1] | Huang, Z.-X. (Huang, Z.-X..) ^[2] | Liu, S.-X. (Liu, S.-X..) ^[3]

Indexed by：

Scopus PKU CSCD

Abstract：

The　title　complex　Cd(dppf)Br2　(dppf=1,1′-bis(diphenylphosphino)ferrocene)　(C34H28Br2　P2CdFe,　Mr=826.57)　has　been　synthesized　and　characterized　by　X-ray　diffraction.　The　crystal　is　in　monoclinic,　space　group　C2/c　with　cell　parameters:　a　=　34.285(4),　b　=　10.050(1),　c　=　18.697(2)　Å,　β=　98.843(3)°,　V　=　6366(1)Å3,　Z　=　8,　Dc=　1.725g/cm3,　λ　(MoKα)　=　0.71073　Å,　μ=3.757mm-1,　F(000)=3248.　The　final　refinement　with　4469　observed　reflections　and　361　parameters　gave　R=0.0584　and　wR=0.1522.　The　1,1′　-bis(diphenylphosphino)ferrocene　group　is　connected　to　the　Cd　atom　as　a　bidentate　ligand.　The　Cd　atom　has　a　distorted　tetrahedral　coordination.

Keyword：

1,1′ -bis(diphenylphosphino)ferrocene; Cadmium complex; Crystal structure; Synthesis

Community：

[ 1 ] [Wang, X.-L.]Department of Chemistry, Fuzhou University, Fuzhou 350002, China
[ 2 ] [Huang, Z.-X.]Department of Chemistry, Fuzhou University, Fuzhou 350002, China
[ 3 ] [Liu, S.-X.]Department of Chemistry, Fuzhou University, Fuzhou 350002, China

Reprint 's Address：

[Huang, Z.-X.]Department of Chemistry, Fuzhou University, Fuzhou 350002, China

Email：

Show more details

Related Keywords：

Source ：

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY

ISSN： 0254-5861

CN： 35-1112/TQ

Year： 2001

Issue： 6

Volume： 20

Page： 486-488

0 . 1 8 4

JCR@2001

5 . 9 0 0

JCR@2023

JCR Journal Grade：4

Cited Count：

WoS CC Cited Count：

SCOPUS Cited Count：

ESI Highly Cited Papers on the List： 0 Unfold All

WanFang Cited Count：

Chinese Cited Count：

30 Days PV： 2

Affiliated Colleges：

Get Fulltext

Library Discovery Baidu Scholar Search SCOPUS

Type
Departments

All Years Choose Year From to