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[期刊论文]

Preparation of MCM-41 surface neopentylzirconium and zirconia

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author:

Wang, XX (Wang, XX.) [1] (Scholars:王绪绪) | Zhao, HX (Zhao, HX.) [2] | Fu, XZ (Fu, XZ.) [3] (Scholars:付贤智)

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Scopus SCIE PKU CSCD

Abstract:

-Zr[CH2C(CH3)(3)](2) groups were grafted on surface of MCM-41 by a reaction with the surface hydroxyls in a high vacuum system for the first time. Hydrolysis or oxidation of the grafted groups resulted in richness of zirconium on the surface of MCM-41. The properties and composition of the materials were characterized by elemental analysis, FTIR, solid-state NMR, XRD and pyridine adsorption. The results showed that the catalytic and adsorptive performance of the grafted ZrMCM-41 was better than that of the hydrothermally synthesized ZrMCM-41.

Keyword:

chemical grafting preparation tetraneopentylzirconium ZrMCM-41

Community:

  • [ 1 ] Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Peoples R China
  • [ 2 ] Fuzhou Univ, Dept Chem, Fuzhou 350002, Peoples R China

Reprint 's Address:

  • 王绪绪

    [Wang, XX]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Peoples R China

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Version:

Source :

CHINESE JOURNAL OF INORGANIC CHEMISTRY

ISSN: 1001-4861

CN: 32-1185/O6

Year: 2001

Issue: 1

Volume: 17

Page: 83-88

0 . 3 0 1

JCR@2001

0 . 8 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:4

Cited Count:

WoS CC Cited Count: 7

30 Days PV: 3

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