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Abstract:
-Zr[CH2C(CH3)(3)](2) groups were grafted on surface of MCM-41 by a reaction with the surface hydroxyls in a high vacuum system for the first time. Hydrolysis or oxidation of the grafted groups resulted in richness of zirconium on the surface of MCM-41. The properties and composition of the materials were characterized by elemental analysis, FTIR, solid-state NMR, XRD and pyridine adsorption. The results showed that the catalytic and adsorptive performance of the grafted ZrMCM-41 was better than that of the hydrothermally synthesized ZrMCM-41.
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CHINESE JOURNAL OF INORGANIC CHEMISTRY
ISSN: 1001-4861
CN: 32-1185/O6
Year: 2001
Issue: 1
Volume: 17
Page: 83-88
0 . 3 0 1
JCR@2001
0 . 8 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
JCR Journal Grade:4
Affiliated Colleges: