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author:

Xu, HB (Xu, HB.) [1] | Wang, XX (Wang, XX.) [2] (Scholars:王绪绪) | Fu, XZ (Fu, XZ.) [3] (Scholars:付贤智) | Xie, LL (Xie, LL.) [4] (Scholars:谢莉莉) | Li, DZ (Li, DZ.) [5] (Scholars:李旦振) | Liu, P (Liu, P.) [6] (Scholars:刘平)

Indexed by:

Scopus SCIE PKU CSCD

Abstract:

A mesoporous MCM-41 molecular sieve richened tin on the surface was prepared by a grafting reaction of SnBu4 on the surface of MCM-41 in vacuum followed by a treatment in flow of oxygen. Compared to SnMCM-41 with comparable ratio of Si/Sn(Si/Snapproximate to100) prepared by the mechanical commixture of nanometer SnO2 with MCM-41, the use of the impregnation of MCM-41 with SnCl4 solution as well as the hydrothermal synthesis route, the obtained sample had better hydrothermal stability and, presented better catalytic activity, higher selectivity of diphenol and higher chemical availability of H2O2 in hydroxylation reaction of the phenol. Some optimal conditions of the reaction were also investigated in the paper.

Keyword:

hydroxylation reaction of phenol mesoporous molecular sieve preparation surface organometallic chemistry

Community:

  • [ 1 ] Fuzhou Univ, Res Inst Photocatalysis, Fuzhou 350002, Peoples R China

Reprint 's Address:

  • 王绪绪

    [Wang, XX]Fuzhou Univ, Res Inst Photocatalysis, Fuzhou 350002, Peoples R China

Email:

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Source :

CHINESE JOURNAL OF INORGANIC CHEMISTRY

ISSN: 1001-4861

CN: 32-1185/O6

Year: 2003

Issue: 5

Volume: 19

Page: 473-479

0 . 5 3 5

JCR@2003

0 . 8 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:4

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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