The　preparation　of　eight　metallophthalocyanine　complexes　substituted　by　N-piperidineethanol　was　achieved　by　tetramerization　of　3-[2-(piperidin-1-yl)ethoxyl]　phthalonitrile　and　4-[2-(piperidin-1-yl)ethoxyl]phthalonitrile　in　the　presence　of　a　metal　salt　with　n-pentanol　as　solvent　and　DBU　as　catalyst,　respectively.　These　complexes　were　characterized　by　IR,　elemental　analysis,　H-1　NMR　and　mass　spectra.　Some　properties　such　as　UV/visible　absorption　spectra,　rate　of　singlet　oxygen　yields,　fluorescence　spectra　and　quantum　yields　were　examined　and　discussed.