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author:

Wu Ren-Ping (Wu Ren-Ping.) [1] (Scholars:吴任平) | Guo Jin-Yu (Guo Jin-Yu.) [2] | Chen Zhu-Ling (Chen Zhu-Ling.) [3] (Scholars:陈珠灵) | Yu Yan (Yu Yan.) [4] (Scholars:于岩)

Indexed by:

SCIE CSCD

Abstract:

Recoverable TiO2 photocatalysis material supported by silicon powder was prepared with sol-gel method, afterwards the silica gol and sodium silicate were used as molding binder respectively to investigate their effects (including binder type and binder addition quantity) on the crystal structure and catalysis properties of photocatalyst. In this work, the catalysis activity was defined as the degradation rate of methyl orange solution upon ultraviolet lamp irradiation, and the specific areas were determined with nitrogen desorption method. TiO2 crystal form was measured with X-ray powder diffraction and their micro-morphology was observed with SEM. Experimental results indicate that these two binders do not affect the crystal form transformation of TiO2, but silica gol can increase the specific surface area of TiO2 photocatalyst obviously and the addition of sodium silicate can decrease it. In all, silica gol is a better candidate than sodium silicate for higher catalysis property. In conclusion, 6% silica gol is the optimal addition concentration. Under this condition, the ratio of anatase to rutile TiO2 is 64:36, the specific area is 29.67 m(2)/g, and as expected, the degradation rate of methyl orange could be as high as 90% after irradiation for 5 days.

Keyword:

binder silica sol silicon powder sodium silicate TiO2 photocatalyst

Community:

  • [ 1 ] [Wu Ren-Ping]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350002, Peoples R China
  • [ 2 ] [Guo Jin-Yu]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350002, Peoples R China
  • [ 3 ] [Chen Zhu-Ling]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350002, Peoples R China
  • [ 4 ] [Yu Yan]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350002, Peoples R China

Reprint 's Address:

  • 于岩

    [Yu Yan]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350002, Peoples R China

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Source :

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY

ISSN: 0254-5861

CN: 35-1112/TQ

Year: 2008

Issue: 10

Volume: 27

Page: 1245-1249

0 . 6 4 3

JCR@2008

5 . 9 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:3

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 6

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