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author:

Zhan Ying-Ying (Zhan Ying-Ying.) [1] (Scholars:詹瑛瑛) | Cai Guo-Hui (Cai Guo-Hui.) [2] (Scholars:蔡国辉) | Zheng Yong (Zheng Yong.) [3] (Scholars:郑勇) | Shen Xiao-Nue (Shen Xiao-Nue.) [4] | Zheng Ying (Zheng Ying.) [5] | Wei Ke-Mei (Wei Ke-Mei.) [6]

Indexed by:

Scopus SCIE PKU CSCD

Abstract:

A sol-gel process was employed to prepare SiC precursors, using tetraethyl orthosilicate (TEOS) and sucrose as raw materials. And oxalic acid, ferric nitrate, and nickel nitrate were added respectively as catalyst for hydrolysis and polymeration reactions. The effects of catalyst, reaction temperature, and reaction time on the gel formation were studied. The results showed that ferric nitrate was optimal for gel formation. SiC of 133 m(2) . g(-1) was obtained by further carbonthermal reduction of the xerogel from the sol-gel system involved ferric nitrate, at 1350 degrees C in an Ar flow for 10 h. Such SiC was then used as catalyst support for CO oxidation. Wet impregnation method was adopted to obtain Pt/SiC catalyst. The as-prepared Pt/SiC catalyst showed good activity and stability for CO oxidation. It was also found that its performance could be improved significantly with the synergistic action of Ni promoter.

Keyword:

CO oxidation high surface area silicon carbide sol-gel support

Community:

  • [ 1 ] [Zhan Ying-Ying]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Peoples R China
  • [ 2 ] [Cai Guo-Hui]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Peoples R China
  • [ 3 ] [Zheng Yong]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Peoples R China
  • [ 4 ] [Wei Ke-Mei]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Peoples R China
  • [ 5 ] [Shen Xiao-Nue]Fujian Normal Univ, Coll Chem & Mat Sci, Fuzhou 350007, Peoples R China
  • [ 6 ] [Zheng Ying]Fujian Normal Univ, Coll Chem & Mat Sci, Fuzhou 350007, Peoples R China

Reprint 's Address:

  • 魏可镁

    [Wei Ke-Mei]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Peoples R China

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Source :

ACTA PHYSICO-CHIMICA SINICA

ISSN: 1000-6818

CN: 11-1892/O6

Year: 2008

Issue: 1

Volume: 24

Page: 171-175

0 . 6 7 3

JCR@2008

1 0 . 8 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:4

Cited Count:

WoS CC Cited Count: 5

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 4

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