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Abstract:
Citric acid (CA) was used to modify graphited activated carbon (AC) for improving size distribution of Ru particles and catalytic activity of the Ru/AC catalyst. The influence of CA on the texture of AC and Ru/AC, Ru distribution and catalytic activity were investigated. TEM, TGA, TPD-MS, CO pulse chemisorption and N(2) physi-sorption indicate that CA modified AC creates more functional groups and thus more homogeneous dispersion of Ru nanoparticles. TEM images show most of the Ru particles were ca. 2-2.5 nm for the CA4 + Ru4/AC catalyst. The increase of ammonia synthesis activity for Ru-Ba-K/AC catalyst is more than 16% when the content of CA in AC is 4 wt.% at 673 K and 10,000 h(-1).
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CATALYSIS LETTERS
ISSN: 1011-372X
Year: 2008
Issue: 1-2
Volume: 126
Page: 134-141
1 . 8 6 7
JCR@2008
2 . 3 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
JCR Journal Grade:2
Cited Count:
WoS CC Cited Count: 15
SCOPUS Cited Count: 14
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1
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