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author:

Ni, Jun (Ni, Jun.) [1] (Scholars:倪军) | Wang, Rong (Wang, Rong.) [2] (Scholars:王榕) | Lin, Jianxin (Lin, Jianxin.) [3] (Scholars:林建新) | Wei, Kemei (Wei, Kemei.) [4]

Indexed by:

EI Scopus SCIE

Abstract:

Citric acid (CA) was used to modify graphited activated carbon (AC) for improving size distribution of Ru particles and catalytic activity of the Ru/AC catalyst. The influence of CA on the texture of AC and Ru/AC, Ru distribution and catalytic activity were investigated. TEM, TGA, TPD-MS, CO pulse chemisorption and N(2) physi-sorption indicate that CA modified AC creates more functional groups and thus more homogeneous dispersion of Ru nanoparticles. TEM images show most of the Ru particles were ca. 2-2.5 nm for the CA4 + Ru4/AC catalyst. The increase of ammonia synthesis activity for Ru-Ba-K/AC catalyst is more than 16% when the content of CA in AC is 4 wt.% at 673 K and 10,000 h(-1).

Keyword:

Activity Ammonia synthesis Citric acid Dispersion Ruthenium

Community:

  • [ 1 ] [Ni, Jun]Fuzhou Univ, Natl Res Ctr Chem Fertilizer Catalysts, Fuzhou 350002, Fujian, Peoples R China
  • [ 2 ] [Wang, Rong]Fuzhou Univ, Natl Res Ctr Chem Fertilizer Catalysts, Fuzhou 350002, Fujian, Peoples R China
  • [ 3 ] [Lin, Jianxin]Fuzhou Univ, Natl Res Ctr Chem Fertilizer Catalysts, Fuzhou 350002, Fujian, Peoples R China
  • [ 4 ] [Wei, Kemei]Fuzhou Univ, Natl Res Ctr Chem Fertilizer Catalysts, Fuzhou 350002, Fujian, Peoples R China

Reprint 's Address:

  • 魏可镁

    [Wei, Kemei]Fuzhou Univ, Natl Res Ctr Chem Fertilizer Catalysts, 523 Gongye Rd, Fuzhou 350002, Fujian, Peoples R China

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Source :

CATALYSIS LETTERS

ISSN: 1011-372X

Year: 2008

Issue: 1-2

Volume: 126

Page: 134-141

1 . 8 6 7

JCR@2008

2 . 3 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:2

Cited Count:

WoS CC Cited Count: 15

SCOPUS Cited Count: 14

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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