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Abstract:
Citric acid (CA) was used to modify graphited activated carbon (AC) for improving size distribution of Ru particles and catalytic activity of the Ru/AC catalyst. The influence of CA on the texture of AC and Ru/AC, Ru distribution and catalytic activity were investigated. TEM, TGA, TPD-MS, CO pulse chemisorption and N2 physisorption indicate that CA modified AC creates more functional groups and thus more homogeneous dispersion of Ru nanoparticles. TEM images show most of the Ru particles were ca. 2-2.5 nm for the CA4 + Ru4/AC catalyst. The increase of ammonia synthesis activity for Ru-Ba-K/AC catalyst is more than 16% when the content of CA in AC is 4 wt.% at 673 K and 10,000 h-1. © 2008 Springer Science+Business Media, LLC.
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Catalysis Letters
ISSN: 1011-372X
Year: 2008
Issue: 1-2
Volume: 126
Page: 134-141
1 . 8 6 7
JCR@2008
2 . 3 0 0
JCR@2023
JCR Journal Grade:2
Cited Count:
SCOPUS Cited Count: 14
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
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30 Days PV: 0
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