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Recently, 2-(dibutyiamino)ethanol (DBAE) was reported to be a more efficient co-reactant than the widely used tripropylamine (TPrA) for electrochemiluminescence (ECL) of Ru(bpy)(3)(2+). Therefore, the new Ru(bpy)(3)(2+)/DBAE ECL system seemed to be great potential for its application in analytical chemistry. Dopamine (DA) was found to be able to inhibit the ECL of Ru(bpy)(3)(2+)/DBAE system. Under the optimum conditions, the logarithmic plot of the inhibited ECL versus the concentration of DA was linear in the range of 5 x 10(-10)-7 x 10(-7) M with the detection limit of 4.0 x 10(-11) M. A mechanism based on the quenching of reductive-form DBAE by DA-oxidation products was proposed, which was quite different from the mechanism for Ru(bpy)(3)(2+)/TPrA/DA system reported previously. (C) 2009 Elsevier B.V. All rights reserved .
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ELECTROCHEMISTRY COMMUNICATIONS
ISSN: 1388-2481
Year: 2009
Issue: 8
Volume: 11
Page: 1579-1582
4 . 2 4 3
JCR@2009
4 . 7 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
JCR Journal Grade:1
CAS Journal Grade:1
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