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[期刊论文]

Mechanism for inhibition of Ru(bpy)(3)(2+)/DBAE electrochemiluminescence system by dopamine

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author:

Xue, Lingling (Xue, Lingling.) [1] | Guo, Longhua (Guo, Longhua.) [2] | Qiu, Bin (Qiu, Bin.) [3] (Scholars:邱彬) | Unfold

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Abstract:

Recently, 2-(dibutyiamino)ethanol (DBAE) was reported to be a more efficient co-reactant than the widely used tripropylamine (TPrA) for electrochemiluminescence (ECL) of Ru(bpy)(3)(2+). Therefore, the new Ru(bpy)(3)(2+)/DBAE ECL system seemed to be great potential for its application in analytical chemistry. Dopamine (DA) was found to be able to inhibit the ECL of Ru(bpy)(3)(2+)/DBAE system. Under the optimum conditions, the logarithmic plot of the inhibited ECL versus the concentration of DA was linear in the range of 5 x 10(-10)-7 x 10(-7) M with the detection limit of 4.0 x 10(-11) M. A mechanism based on the quenching of reductive-form DBAE by DA-oxidation products was proposed, which was quite different from the mechanism for Ru(bpy)(3)(2+)/TPrA/DA system reported previously. (C) 2009 Elsevier B.V. All rights reserved .

Keyword:

2-(Dibutylamino)ethanol Dopamine Electrochemiluminescence Inhibition Ru(bpy)(3)(2+)

Community:

  • [ 1 ] [Xue, Lingling]Fuzhou Univ, Dept Chem, Minist Educ, Key Lab Anal & Detect Technol Food Safety, Fuzhou 350002, Peoples R China
  • [ 2 ] [Guo, Longhua]Fuzhou Univ, Dept Chem, Minist Educ, Key Lab Anal & Detect Technol Food Safety, Fuzhou 350002, Peoples R China
  • [ 3 ] [Qiu, Bin]Fuzhou Univ, Dept Chem, Minist Educ, Key Lab Anal & Detect Technol Food Safety, Fuzhou 350002, Peoples R China
  • [ 4 ] [Lin, Zhenyu]Fuzhou Univ, Dept Chem, Minist Educ, Key Lab Anal & Detect Technol Food Safety, Fuzhou 350002, Peoples R China
  • [ 5 ] [Chen, Guonan]Fuzhou Univ, Dept Chem, Minist Educ, Key Lab Anal & Detect Technol Food Safety, Fuzhou 350002, Peoples R China

Reprint 's Address:

  • 林振宇

    [Lin, Zhenyu]Fuzhou Univ, Dept Chem, Minist Educ, Key Lab Anal & Detect Technol Food Safety, Fuzhou 350002, Peoples R China

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Source :

ELECTROCHEMISTRY COMMUNICATIONS

ISSN: 1388-2481

Year: 2009

Issue: 8

Volume: 11

Page: 1579-1582

4 . 2 4 3

JCR@2009

4 . 7 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 65

SCOPUS Cited Count: 65

30 Days PV: 0

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