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author:

Luo, Xiaojun (Luo, Xiaojun.) [1] | Wang, Rong (Wang, Rong.) [2] (Scholars:王榕) | Ni, Jun (Ni, Jun.) [3] (Scholars:倪军) | Lin, Jianxin (Lin, Jianxin.) [4] (Scholars:林建新) | Lin, Bingyu (Lin, Bingyu.) [5] (Scholars:林炳裕) | Xu, Xianming (Xu, Xianming.) [6] | Wei, Kemei (Wei, Kemei.) [7]

Indexed by:

EI Scopus SCIE

Abstract:

A series of CeO2-La2O3 supported ruthenium catalysts were prepared by co-precipitation method and the as-obtained samples were characterized by N-2 physisorption, X-ray diffraction, CO chemisorption, H-2-TPR, H-2-TPD and XPS. The activity test shows that ammonia concentration of the catalyst with 10% La is 13.9% at 10 MPa, 10,000 h(-1), 450 A degrees C, which is 17% higher than that of Ru/CeO2. La doping can improve the activity of Ru-ceria catalyst for ammonia synthesis by facilitating the reduction of oxygen which subsists in the cerium oxide surface. In addition, it can be realized that the test of catalyst stability proves the stability performance of Ru/CeO2-La2O3 catalyst within the reaction time of 55 h.

Keyword:

Ammonia synthesis CeO2-La2O3 Co-precipitation La doping Ruthenium

Community:

  • [ 1 ] [Luo, Xiaojun]Fuzhou Univ, Natl Res Ctr Chem Fertilizer Catalysts, Fuzhou 350002, Fujian, Peoples R China
  • [ 2 ] [Wang, Rong]Fuzhou Univ, Natl Res Ctr Chem Fertilizer Catalysts, Fuzhou 350002, Fujian, Peoples R China
  • [ 3 ] [Ni, Jun]Fuzhou Univ, Natl Res Ctr Chem Fertilizer Catalysts, Fuzhou 350002, Fujian, Peoples R China
  • [ 4 ] [Lin, Jianxin]Fuzhou Univ, Natl Res Ctr Chem Fertilizer Catalysts, Fuzhou 350002, Fujian, Peoples R China
  • [ 5 ] [Lin, Bingyu]Fuzhou Univ, Natl Res Ctr Chem Fertilizer Catalysts, Fuzhou 350002, Fujian, Peoples R China
  • [ 6 ] [Wei, Kemei]Fuzhou Univ, Natl Res Ctr Chem Fertilizer Catalysts, Fuzhou 350002, Fujian, Peoples R China
  • [ 7 ] [Xu, Xianming]Petr Chem Res Ctr Daqing, China Petr Chem Res Inst Daqing, Daqing 163714, Heilongjiang, Peoples R China

Reprint 's Address:

  • 王榕

    [Wang, Rong]Fuzhou Univ, Natl Res Ctr Chem Fertilizer Catalysts, 523 Gongye Rd, Fuzhou 350002, Fujian, Peoples R China

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Source :

CATALYSIS LETTERS

ISSN: 1011-372X

Year: 2009

Issue: 3-4

Volume: 133

Page: 382-387

2 . 0 2 1

JCR@2009

2 . 3 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:2

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 63

SCOPUS Cited Count: 68

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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