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author:

Wang, Ziqing (Wang, Ziqing.) [1] | Lin, Jianxin (Lin, Jianxin.) [2] (Scholars:林建新) | Wang, Rong (Wang, Rong.) [3] (Scholars:王榕) | Wei, Kemei (Wei, Kemei.) [4]

Indexed by:

EI Scopus SCIE

Abstract:

Ammonia synthesis reaction was performed over a novel ruthenium catalyst supported on perovskite-type BaTiO3. It was quite worth noting that Ru/BaTiO3 catalyst exhibited outstanding activity for ammonia synthesis. The results of XRD, CO2-TPD, H-2-TPR and TEM indicated that the strong metal-support interaction (SMSI) between a partially reduced support and Ru combined with strong basicity of support was responsible for such high catalytic activity. The electrons could be easily transferred from the support to the surface of Ru particles by the SMSI effect facilitated the cleavage of NN and greatly enhanced the activity for ammonia synthesis. Crown Copyright (C) 2012 Published by Elsevier B.V. All rights reserved.

Keyword:

Ammonia synthesis Basicity Perovskite Ruthenium catalyst SMSI

Community:

  • [ 1 ] [Wang, Ziqing]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Fujian, Peoples R China
  • [ 2 ] [Lin, Jianxin]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Fujian, Peoples R China
  • [ 3 ] [Wang, Rong]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Fujian, Peoples R China
  • [ 4 ] [Wei, Kemei]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Fujian, Peoples R China

Reprint 's Address:

  • 林建新

    [Lin, Jianxin]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Fujian, Peoples R China

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Source :

CATALYSIS COMMUNICATIONS

ISSN: 1566-7367

Year: 2013

Volume: 32

Page: 11-14

3 . 3 2

JCR@2013

3 . 4 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count: 49

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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