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author:

Qiu, Shangchang (Qiu, Shangchang.) [1] | Zheng, Yuying (Zheng, Yuying.) [2] (Scholars:郑玉婴) | Zeng, Anran (Zeng, Anran.) [3] | Guo, Yong (Guo, Yong.) [4]

Indexed by:

EI Scopus SCIE

Abstract:

Non-isothermal crystallization kinetics of isotactic polypropylene (iPP) was simulated with the assumption that the non-isothermal crystallization process was composed of some finite isothermal crystallization processes, while each isothermal crystallization process consists of three main steps induction, nucleation and crystal growth. In the simulation, induction time was taken into account, allowing one to make predictions on the start of the non-isothermal crystallization of iPP: nuclei density was treated as a function of temperature: the Hoffman-Lauritzen theory was employed to describe the spherulite growth rate varied with temperature, and the relative crystallinity was determined by the equation of Kolmogorov. Finally, model prediction was verified by quantitative comparison between the theoretical results with the experimental results. (C) 2010 Elsevier B.V. All rights reserved.

Keyword:

Isotactic polypropylene (iPP) Non-isothermal crystallization kinetics Relative crystallinity Simulation

Community:

  • [ 1 ] [Qiu, Shangchang]Fuzhou Univ, Coll Chem & Chem Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 2 ] [Zheng, Yuying]Fuzhou Univ, Coll Chem & Chem Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 3 ] [Zeng, Anran]Fuzhou Univ, Coll Chem & Chem Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 4 ] [Guo, Yong]Fuzhou Univ, Coll Chem & Chem Engn, Fuzhou 350108, Fujian, Peoples R China

Reprint 's Address:

  • 郑玉婴

    [Zheng, Yuying]Fuzhou Univ, Coll Chem & Chem Engn, Fuzhou 350108, Fujian, Peoples R China

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Source :

THERMOCHIMICA ACTA

ISSN: 0040-6031

Year: 2011

Issue: 1-2

Volume: 512

Page: 28-33

1 . 8 0 5

JCR@2011

3 . 1 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:3

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count: 16

SCOPUS Cited Count: 16

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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