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Abstract:
Non-isothermal crystallization kinetics of isotactic polypropylene (iPP) was simulated with the assumption that the non-isothermal crystallization process was composed of some finite isothermal crystallization processes, while each isothermal crystallization process consists of three main steps induction, nucleation and crystal growth. In the simulation, induction time was taken into account, allowing one to make predictions on the start of the non-isothermal crystallization of iPP: nuclei density was treated as a function of temperature: the Hoffman-Lauritzen theory was employed to describe the spherulite growth rate varied with temperature, and the relative crystallinity was determined by the equation of Kolmogorov. Finally, model prediction was verified by quantitative comparison between the theoretical results with the experimental results. (C) 2010 Elsevier B.V. All rights reserved.
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THERMOCHIMICA ACTA
ISSN: 0040-6031
Year: 2011
Issue: 1-2
Volume: 512
Page: 28-33
1 . 8 0 5
JCR@2011
3 . 1 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
JCR Journal Grade:3
CAS Journal Grade:4
Cited Count:
WoS CC Cited Count: 16
SCOPUS Cited Count: 16
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 2
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