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Abstract:
The effect of sodium salicylate (NaSal) on the formation and properties of wormlike micelles in aqueous solutions of 2-hydroxyl-propanediyl-a,.-bis(dimethyldodecylammonium bromide) (12-3(OH)-12) and propanediyl-alpha,omega-bis(dimethyldodecylammonium bromide) (12-3-12) at a surfactant concentration of 50 mmol . L-1 was investigated using steady-state and frequency sweep rheological measurements. In the absence of a salt, 12-3(OH)-12 or 12-3-12 only produced spherical or small rod-like micelles at 50 mmol . L-1. The addition of NaSal promoted micellar growth yielding wormlike micelles in both systems. 12-3 (OH)-12 showed a more sensitive response to the added NaSal compared with 12-3-12 and formed wormlike micelles at relatively lower salt concentrations. Moreover, the wormlike micelles formed by 12-3 (OH)-12 were longer than those formed by 12-3-12, resulting in higher viscosity for the former solution. These were attributed to the hydrogen bonding interactions between the hydroxyl substituted spacers in the 12-3(OH)-12 system, which increased hydration on the aggregate surface and stimulated the dissociation of counterions. The higher charge on the 12-3(OH)-12 micellar surface was strongly associated with Sal-, which led to a tighter packing of the surfactant molecules in the micelles and thus strengthened the intermolecular hydrogen bonding interactions and effectively reinforced the growth of the 12- 3(OH)-12 micelles.
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ACTA PHYSICO-CHIMICA SINICA
ISSN: 1000-6818
CN: 11-1892/O6
Year: 2011
Issue: 4
Volume: 27
Page: 913-917
0 . 7 8
JCR@2011
1 0 . 8 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
JCR Journal Grade:4
CAS Journal Grade:4
Affiliated Colleges:
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