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[期刊论文]

Effect of Sodium Salicylate on the Formation and Properties of Wormlike Micelles in Aqueous Cationic Gemini Surfactant Solutions

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author:

Pei Xiao-Mei (Pei Xiao-Mei.) [1] | Zhao Jian-Xi (Zhao Jian-Xi.) [2] (Scholars:赵剑曦) | Wei Xi-Lian (Wei Xi-Lian.) [3]

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Scopus SCIE PKU CSCD

Abstract:

The effect of sodium salicylate (NaSal) on the formation and properties of wormlike micelles in aqueous solutions of 2-hydroxyl-propanediyl-a,.-bis(dimethyldodecylammonium bromide) (12-3(OH)-12) and propanediyl-alpha,omega-bis(dimethyldodecylammonium bromide) (12-3-12) at a surfactant concentration of 50 mmol . L-1 was investigated using steady-state and frequency sweep rheological measurements. In the absence of a salt, 12-3(OH)-12 or 12-3-12 only produced spherical or small rod-like micelles at 50 mmol . L-1. The addition of NaSal promoted micellar growth yielding wormlike micelles in both systems. 12-3 (OH)-12 showed a more sensitive response to the added NaSal compared with 12-3-12 and formed wormlike micelles at relatively lower salt concentrations. Moreover, the wormlike micelles formed by 12-3 (OH)-12 were longer than those formed by 12-3-12, resulting in higher viscosity for the former solution. These were attributed to the hydrogen bonding interactions between the hydroxyl substituted spacers in the 12-3(OH)-12 system, which increased hydration on the aggregate surface and stimulated the dissociation of counterions. The higher charge on the 12-3(OH)-12 micellar surface was strongly associated with Sal-, which led to a tighter packing of the surfactant molecules in the micelles and thus strengthened the intermolecular hydrogen bonding interactions and effectively reinforced the growth of the 12- 3(OH)-12 micelles.

Keyword:

Cationic gemini surfactant Intermolecular hydrogen bond NaSal Rheological property Wormlike micelle

Community:

  • [ 1 ] [Pei Xiao-Mei]Fuzhou Univ, Coll Chem & Chem Engn, Inst Colloid & Interface Chem, Fuzhou 350108, Peoples R China
  • [ 2 ] [Zhao Jian-Xi]Fuzhou Univ, Coll Chem & Chem Engn, Inst Colloid & Interface Chem, Fuzhou 350108, Peoples R China
  • [ 3 ] [Wei Xi-Lian]Liaocheng Univ, Coll Chem & Chem Engn, Liaocheng 252059, Shandong, Peoples R China

Reprint 's Address:

  • 赵剑曦

    [Zhao Jian-Xi]Fuzhou Univ, Coll Chem & Chem Engn, Inst Colloid & Interface Chem, Fuzhou 350108, Peoples R China

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Source :

ACTA PHYSICO-CHIMICA SINICA

ISSN: 1000-6818

CN: 11-1892/O6

Year: 2011

Issue: 4

Volume: 27

Page: 913-917

0 . 7 8

JCR@2011

1 0 . 8 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:4

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count: 9

30 Days PV: 1

操作日志

管理员  2024-07-26 18:38:26  更新被引

管理员  2020-11-13 01:52:19  创建

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