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author:

Pei, X.-M. (Pei, X.-M..) [1] | Zhao, J.-X. (Zhao, J.-X..) [2] | Wei, X.-L. (Wei, X.-L..) [3]

Indexed by:

Scopus PKU CSCD

Abstract:

The effect of sodium salicylate (NaSal) on the formation and properties of wormlike micelles in aqueous solutions of 2-hydroxyl-propanediyl-α,ω-bis(dimethyldodecylammonium bromide) (12-3(OH)-12) and propanediyl-α,ω-bis(dimethyldodecylammonium bromide) (12-3-12) at a surfactant concentration of 50 mmol·L-1 was investigated using steady-state and frequency sweep rheological measurements. In the absence of a salt, 12-3(OH)-12 or 12-3-12 only produced spherical or small rod-like micelles at 50 mmol· L-1. The addition of NaSal promoted micellar growth yielding wormlike micelles in both systems. 12-3 (OH)-12 showed a more sensitive response to the added NaSal compared with 12-3-12 and formed wormlike micelles at relatively lower salt concentrations. Moreover, the wormlike micelles formed by 12-3 (OH)-12 were longer than those formed by 12-3-12, resulting in higher viscosity for the former solution. These were attributed to the hydrogen bonding interactions between the hydroxyl substituted spacers in the 12-3(OH)-12 system, which increased hydration on the aggregate surface and stimulated the dissociation of counterions. The higher charge on the 12-3(OH)-12 micellar surface was strongly associated with Sal-, which led to a tighter packing of the surfactant molecules in the micelles and thus strengthened the intermolecular hydrogen bonding interactions and effectively reinforced the growth of the 12-3(OH)-12 micelles. © Editorial office of Acta Physico-Chimica Sinica.

Keyword:

Cationic gemini surfactant; Intermolecular hydrogen bond; NaSal; Rheological property; Wormlike micelle

Community:

  • [ 1 ] [Pei, X.-M.]Institute of Colloid and Interface Chemistry, College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108, China
  • [ 2 ] [Zhao, J.-X.]Institute of Colloid and Interface Chemistry, College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108, China
  • [ 3 ] [Wei, X.-L.]College of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252059, Shandong Province, China

Reprint 's Address:

  • [Zhao, J.-X.]Institute of Colloid and Interface Chemistry, College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108, China

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Source :

Acta Physico - Chimica Sinica

ISSN: 1000-6818

Year: 2011

Issue: 4

Volume: 27

Page: 913-917

0 . 7 8

JCR@2011

1 0 . 8 0 0

JCR@2023

JCR Journal Grade:4

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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