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Abstract:
Phosphate removal to a hydrothermally modified fumed silica and pulverized oyster shell material for use in wastewater treatments were made. Sorption data modeling (pH's 3-11, P concentrations of 3, 5, 10, 15, 20, & 25 mg/L, and at an ambient temperature of 23 degrees C) indicate that an optimal removal of P occurs at pH 11. Three kinetic models were also applied (a pseudo-first-order Lagergren kinetic model, a pseudo-second-order (PSO) kinetic and Elovich) and indicate that a PSO model best describes P-removal. In addition, an application of the Weber and Morris intra-particle diffusion model indicates that external mass transfer and intra-particle diffusion were both involved in the rate-determining step. Langmuir, Freundlich modeling of the sorption data also indicate that the heterogeneous Freundlich sorption site model best describes the data although Langmuir data also fit with data tailing suggesting data are not linear. The data collected indicates that the hydrothermally modified fumed silica and pulverized oyster shell material is suitable for use in wastewater treatment, with P-removal to the solids being preferential and spontaneous.
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PLOS ONE
ISSN: 1932-6203
Year: 2013
Issue: 4
Volume: 8
3 . 5 3 4
JCR@2013
2 . 9 0 0
JCR@2023
ESI Discipline: MULTIDISCIPLINARY;
JCR Journal Grade:1
CAS Journal Grade:3
Cited Count:
WoS CC Cited Count: 34
SCOPUS Cited Count: 51
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 3
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