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author:

Li Heng-Dong (Li Heng-Dong.) [1] | Su Xiao-Long (Su Xiao-Long.) [2] | Chen Ping-Hua (Chen Ping-Hua.) [3] | Xie Li-Li (Xie Li-Li.) [4] (Scholars:谢莉莉) | Yuan Yao-Feng (Yuan Yao-Feng.) [5] (Scholars:袁耀锋)

Indexed by:

EI Scopus SCIE PKU CSCD

Abstract:

Recently, great interest has been generated in the synthesis and study of heterocyclic derivatives containing one or more ferrocenes, since these derivatives have potential applications as new functional materials in several areas. As a stable and readily oxidizable organometallic complex, ferrocne has been widely employed in multifunctional systems, which have exhibited potential utilizations in electrochemical sensors, molecular recognition and ethylene oligomerization catalysts. Combining the considerations above, we designed a simple and general approach to synthesis three 5-ferrocenyl-Pyrazoline derivatives(3-5). The structures of all the products were determined by IR, MS, H-1 NMR, C-13 NMR and elemental analysis. The crystal structure of compound 4 was proved by single crystal X-ray analyses. Moreover, compounds 3-5 were characterized by CV, UV-Vis absorption and fluorescence spectrometry. Density functional theory (DFT) calculation was adopted to explain these phenomena. These compounds will be used as electrochemical sensors and ethylene oligomerization catalysts.

Keyword:

Crystal structure Cyclic voltammetry Density functional theory calculation Ferrocenyl dihydropyrazole Spectral property

Community:

  • [ 1 ] [Xie Li-Li]Fuzhou Univ, Fujian Prov Key Lab Photocatalysis, State Key Lab Breeding Base, Fuzhou 350002, Peoples R China
  • [ 2 ] [Yuan Yao-Feng]Fuzhou Univ, Fujian Prov Key Lab Photocatalysis, State Key Lab Breeding Base, Fuzhou 350002, Peoples R China
  • [ 3 ] [Li Heng-Dong]Fuzhou Univ, Dept Chem, Fuzhou 350108, Peoples R China
  • [ 4 ] [Su Xiao-Long]Fuzhou Univ, Dept Chem, Fuzhou 350108, Peoples R China
  • [ 5 ] [Chen Ping-Hua]Fuzhou Univ, Dept Chem, Fuzhou 350108, Peoples R China
  • [ 6 ] [Xie Li-Li]Fuzhou Univ, Dept Chem, Fuzhou 350108, Peoples R China
  • [ 7 ] [Yuan Yao-Feng]Fuzhou Univ, Dept Chem, Fuzhou 350108, Peoples R China

Reprint 's Address:

  • 袁耀锋

    [Yuan Yao-Feng]Fuzhou Univ, Fujian Prov Key Lab Photocatalysis, State Key Lab Breeding Base, Fuzhou 350002, Peoples R China

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Source :

CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE

ISSN: 0251-0790

CN: 22-1131/O6

Year: 2013

Issue: 7

Volume: 34

Page: 1653-1659

0 . 9 5 4

JCR@2013

0 . 7 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:3

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count: 4

SCOPUS Cited Count: 4

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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