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Abstract:
High thermally stable mesoporous alumina doped with lanthanum was synthesized using inorganic nitrates as precursors and employing pluronic P123 (P123, (EO20PO70EO20, EO=ethylene oxide, PO=propylene oxide)) as a structure-directing agent. After calcination at 400 degrees C, the resultant lanthanum doped alumina exhibited a gamma-Al2O3 phase, which was the same as pure alumina. After the thermal treatment up to 1200 degrees C, La-doped Al2O3 generated only one phase of theta-Al2O3 rather than two mixed phase of theta-Al2O3 and alpha-Al2O3 and the surface area could still maintain 101 m(2)/g with a keeping pore volume of 0.66 cm(3)/g. The excellent thermal stability was explained by the titration of strong Lewis acid sites of gamma-Al2O3 with the assistance of highly dispersed lanthanum species covering on alumina. Furthermore, the lanthanum modified mesoporous alumina was preliminarily employed as a stable support for Pd in the catalytic oxidation of C3H8.
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JOURNAL OF RARE EARTHS
ISSN: 1002-0721
CN: 11-2788/TF
Year: 2013
Issue: 11
Volume: 31
Page: 1081-1084
1 . 3 4 2
JCR@2013
5 . 2 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
JCR Journal Grade:2
CAS Journal Grade:4
Cited Count:
WoS CC Cited Count: 8
SCOPUS Cited Count: 10
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 2
Affiliated Colleges: