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author:

Jiang Lilong (Jiang Lilong.) [1] (Scholars:江莉龙) | Wang Yuling (Wang Yuling.) [2] | Wang Xiuyun (Wang Xiuyun.) [3] (Scholars:王秀云) | Luo Yongjin (Luo Yongjin.) [4] | Cao Yanning (Cao Yanning.) [5] (Scholars:曹彦宁) | Wei Kemei (Wei Kemei.) [6]

Indexed by:

EI Scopus SCIE CSCD

Abstract:

High thermally stable mesoporous alumina doped with lanthanum was synthesized using inorganic nitrates as precursors and employing pluronic P123 (P123, (EO20PO70EO20, EO=ethylene oxide, PO=propylene oxide)) as a structure-directing agent. After calcination at 400 degrees C, the resultant lanthanum doped alumina exhibited a gamma-Al2O3 phase, which was the same as pure alumina. After the thermal treatment up to 1200 degrees C, La-doped Al2O3 generated only one phase of theta-Al2O3 rather than two mixed phase of theta-Al2O3 and alpha-Al2O3 and the surface area could still maintain 101 m(2)/g with a keeping pore volume of 0.66 cm(3)/g. The excellent thermal stability was explained by the titration of strong Lewis acid sites of gamma-Al2O3 with the assistance of highly dispersed lanthanum species covering on alumina. Furthermore, the lanthanum modified mesoporous alumina was preliminarily employed as a stable support for Pd in the catalytic oxidation of C3H8.

Keyword:

calcination lanthanum mesoporous alumina rare earths thermal stability

Community:

  • [ 1 ] [Jiang Lilong]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Peoples R China
  • [ 2 ] [Wang Yuling]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Peoples R China
  • [ 3 ] [Wang Xiuyun]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Peoples R China
  • [ 4 ] [Luo Yongjin]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Peoples R China
  • [ 5 ] [Cao Yanning]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Peoples R China
  • [ 6 ] [Wei Kemei]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Peoples R China

Reprint 's Address:

  • 魏可镁

    [Wei Kemei]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Peoples R China

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Source :

JOURNAL OF RARE EARTHS

ISSN: 1002-0721

CN: 11-2788/TF

Year: 2013

Issue: 11

Volume: 31

Page: 1081-1084

1 . 3 4 2

JCR@2013

5 . 2 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:2

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count: 8

SCOPUS Cited Count: 10

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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