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author:

Hua, Nengbin (Hua, Nengbin.) [1] | Chen, Wenzhe (Chen, Wenzhe.) [2] | Liu, Xiaoli (Liu, Xiaoli.) [3] | Yue, Feng (Yue, Feng.) [4]

Indexed by:

EI Scopus SCIE

Abstract:

The isochronal and isothermal crystallization behaviors of Zr70Al12.5Fe17.5 and Zr75Al75Fe17.5 glassy alloys were studied using differential scanning calorimeter (DSC). Under isochronal heating, the two amorphous alloys possessed different primary phases in the initial crystallization. The activation energies for the glass transition and crystallization of Zr75Al75Fe17.5 glassy alloy determined by the Kissinger, Ozawa and Augis-Bennett plots were larger than those of Zr70Al12.5Fe17.5 alloy. Isothermal kinetics of glassy alloys was modeled by the Johnson-Mehl-Avrami equation. For the Zr70Al12.5Fe17.5 glassy alloy, the Avrami exponents were mostly in the range from 2.48 to 2.68, which indicated a constant nucleation rate and a diffusion-controlled three-dimensional growth. The Zr75Al75Fe17.5 glassy alloy exhibited relatively larger Avrami exponents of between 2.72 and 3.07, implying a diffusion-controlled three-dimensional growth with increasing nucleation rate. (C) 2014 Elsevier B.V. All rights reserved.

Keyword:

Activation energy Avrami exponent Crystallization Glassy alloys Zr-Al-Fe alloy

Community:

  • [ 1 ] [Hua, Nengbin]Fujian Univ Technol, Dept Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 2 ] [Chen, Wenzhe]Fujian Univ Technol, Dept Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 3 ] [Liu, Xiaoli]Fujian Univ Technol, Dept Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 4 ] [Yue, Feng]Fujian Univ Technol, Dept Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 5 ] [Hua, Nengbin]Fuzhou Univ, Dept Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 6 ] [Chen, Wenzhe]Fuzhou Univ, Dept Mat Sci & Engn, Fuzhou 350108, Peoples R China

Reprint 's Address:

  • 花能斌

    [Hua, Nengbin]Fujian Univ Technol, Dept Mat Sci & Engn, Fuzhou 350108, Peoples R China

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Source :

JOURNAL OF NON-CRYSTALLINE SOLIDS

ISSN: 0022-3093

Year: 2014

Volume: 388

Page: 10-16

1 . 7 6 6

JCR@2014

3 . 2 0 0

JCR@2023

ESI Discipline: PHYSICS;

ESI HC Threshold:213

JCR Journal Grade:1

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 26

SCOPUS Cited Count: 28

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 4

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