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Abstract:
The isochronal and isothermal crystallization behaviors of Zr 70Al12.5Fe17.5 and Zr75Al 7.5Fe17.5 glassy alloys were studied using differential scanning calorimeter (DSC). Under isochronal heating, the two amorphous alloys possessed different primary phases in the initial crystallization. The activation energies for the glass transition and crystallization of Zr 75Al7.5Fe17.5 glassy alloy determined by the Kissinger, Ozawa and Augis-Bennett plots were larger than those of Zr 70Al12.5Fe17.5 alloy. Isothermal kinetics of glassy alloys was modeled by the Johnson-Mehl-Avrami equation. For the Zr 70Al12.5Fe17.5 glassy alloy, the Avrami exponents were mostly in the range from 2.48 to 2.68, which indicated a constant nucleation rate and a diffusion-controlled three-dimensional growth. The Zr75Al7.5Fe17.5 glassy alloy exhibited relatively larger Avrami exponents of between 2.72 and 3.07, implying a diffusion-controlled three-dimensional growth with increasing nucleation rate. © 2014 Elsevier B.V.
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Journal of Non-Crystalline Solids
ISSN: 0022-3093
Year: 2014
Volume: 388
Page: 10-16
1 . 7 6 6
JCR@2014
3 . 2 0 0
JCR@2023
ESI HC Threshold:213
JCR Journal Grade:1
CAS Journal Grade:3
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ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 2
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