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Under hydrothermal conditions, a series of beta-MnO2 microrod catalysts were fabricated using different manganese precursors (MnSO4, (CH3COO)(2)Mn.4H(2)O, MnCl2.4H(2)O, Mn(NO3)(2).4H(2)O). The as-prepared beta-MnO2 microrods were characterized by powder X-ray diffraction (XRD), N-2 physical adsorption, scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), and Fourier transform infrared spectroscopy (FT-IR). The characterization results showed that the morphologies and crystallinity of MnO2 were mainly determined by the hydrothermal time and temperature. Suitable hydrothermal time and temperature produced well defined beta-MnO2 microrods with high crystallinity. The obtained beta-MnO2 microrod catalysts were applied to degrade different dyes with high concentration (methylene blue (MB), methyl orange (MO), rhodamine B (RB) and acid orange II (AOII)) in the presence of H2O2. The catalytic mechanism was discussed and a Fenton-like reaction mechanism was proposed. High crystallinity and good morphology effectively promoted the catalytic performance of beta-MnO2 microrods. The efficiencies of beta-MnO2 microrods in degradation of different dyes are markedly different. The dye degradation rates followed the order of MB > AOII > RB > MO. Moreover, the beta-MnO2 microrods exhibited high stability in recycling degradation, which suggests promising applications in practical dye pollutant treatment. (C) 2013 Elsevier B.V. All rights reserved.
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CATALYSIS TODAY
ISSN: 0920-5861
Year: 2014
Volume: 224
Page: 154-162
3 . 8 9 3
JCR@2014
5 . 2 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
ESI HC Threshold:268
JCR Journal Grade:1
CAS Journal Grade:2
Cited Count:
WoS CC Cited Count: 95
SCOPUS Cited Count: 103
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1
Affiliated Colleges: