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author:

Yu, Changlin (Yu, Changlin.) [1] | Li, Gao (Li, Gao.) [2] | Wei, Longfu (Wei, Longfu.) [3] | Fan, Qizhe (Fan, Qizhe.) [4] | Shu, Qing (Shu, Qing.) [5] | Yu, Jimmy C. (Yu, Jimmy C..) [6]

Indexed by:

CPCI-S EI Scopus SCIE

Abstract:

Under hydrothermal conditions, a series of beta-MnO2 microrod catalysts were fabricated using different manganese precursors (MnSO4, (CH3COO)(2)Mn.4H(2)O, MnCl2.4H(2)O, Mn(NO3)(2).4H(2)O). The as-prepared beta-MnO2 microrods were characterized by powder X-ray diffraction (XRD), N-2 physical adsorption, scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), and Fourier transform infrared spectroscopy (FT-IR). The characterization results showed that the morphologies and crystallinity of MnO2 were mainly determined by the hydrothermal time and temperature. Suitable hydrothermal time and temperature produced well defined beta-MnO2 microrods with high crystallinity. The obtained beta-MnO2 microrod catalysts were applied to degrade different dyes with high concentration (methylene blue (MB), methyl orange (MO), rhodamine B (RB) and acid orange II (AOII)) in the presence of H2O2. The catalytic mechanism was discussed and a Fenton-like reaction mechanism was proposed. High crystallinity and good morphology effectively promoted the catalytic performance of beta-MnO2 microrods. The efficiencies of beta-MnO2 microrods in degradation of different dyes are markedly different. The dye degradation rates followed the order of MB > AOII > RB > MO. Moreover, the beta-MnO2 microrods exhibited high stability in recycling degradation, which suggests promising applications in practical dye pollutant treatment. (C) 2013 Elsevier B.V. All rights reserved.

Keyword:

beta-MnO2 Catalytic mechanism Dye degradation Hydrothermal condition Microrod catalysts

Community:

  • [ 1 ] [Yu, Changlin]Jiangxi Univ Sci & Technol, Sch Met & Chem Engn, Ganzhou 341000, Jiangxi, Peoples R China
  • [ 2 ] [Wei, Longfu]Jiangxi Univ Sci & Technol, Sch Met & Chem Engn, Ganzhou 341000, Jiangxi, Peoples R China
  • [ 3 ] [Fan, Qizhe]Jiangxi Univ Sci & Technol, Sch Met & Chem Engn, Ganzhou 341000, Jiangxi, Peoples R China
  • [ 4 ] [Shu, Qing]Jiangxi Univ Sci & Technol, Sch Met & Chem Engn, Ganzhou 341000, Jiangxi, Peoples R China
  • [ 5 ] [Yu, Changlin]Carnegie Mellon Univ, Dept Chem, Pittsburgh, PA 15213 USA
  • [ 6 ] [Li, Gao]Carnegie Mellon Univ, Dept Chem, Pittsburgh, PA 15213 USA
  • [ 7 ] [Wei, Longfu]Fuzhou Univ, State Key Lab Breeding Base, Fujian Prov Key Lab Photocatalysis, Fuzhou 350002, Peoples R China
  • [ 8 ] [Yu, Jimmy C.]Chinese Univ Hong Kong, Ctr Novel Funct Mol, Dept Chem, Shatin, Hong Kong, Peoples R China
  • [ 9 ] [Yu, Jimmy C.]Chinese Univ Hong Kong, Environm Sci Programme, Shatin, Hong Kong, Peoples R China

Reprint 's Address:

  • [Yu, Changlin]Jiangxi Univ Sci & Technol, Sch Met & Chem Engn, 86 Hongqi Rd, Ganzhou 341000, Jiangxi, Peoples R China

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Source :

CATALYSIS TODAY

ISSN: 0920-5861

Year: 2014

Volume: 224

Page: 154-162

3 . 8 9 3

JCR@2014

5 . 2 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:268

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 95

SCOPUS Cited Count: 103

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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