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author:

Liu, Dan-Hui (Liu, Dan-Hui.) [1] | Luo, Wei (Luo, Wei.) [2] | Wei, Yu-Zhen (Wei, Yu-Zhen.) [3] | Lin, Chun-Xiang (Lin, Chun-Xiang.) [4] (Scholars:林春香) | Du, Chao-Yang (Du, Chao-Yang.) [5] | Liu, Ming-Hua (Liu, Ming-Hua.) [6]

Indexed by:

Scopus SCIE

Abstract:

Cellulose is a premising raw materials available and can be Modified through a. variety of chemical Modifications to Obtain functional materials. Cellulose-g-acrylamide copolymer was prepared in a homogeneous medium by using N,N-methylenebisacrylamide as crosslinker without any radical initiator under microwave radiation. 1-Butyl-3-methylinidazolium chloride an([Bmim]Cl) ionic liquid is an environment friendly and effective reaction, medium, was chosen to dissolve cellulose and the homogeneous graft polymerization of acrylamide onto cellulose: Due to the effect of microwave heating, the reaction time was significantly shorten: 1 min Microwave heating was adequate, compared with 0.5-5.0 h, as conventional heating was used The influences of monomer concentration, crosslinker dosage, microwave power and reaction time were investigated the obtained cellulose graft copolymer was characterized by ER spectrum, TGA and SEM. A feasible reaction mechanism of grafting based-on microwave heating was put forward.

Keyword:

Acrylamide Cellulose Graft polymerization Homogeneous Ionic liquid Microwave

Community:

  • [ 1 ] [Liu, Dan-Hui]Fuzhou Univ, Coll Environm & Resources, Fuzhou 350002, Peoples R China
  • [ 2 ] [Luo, Wei]Fuzhou Univ, Coll Environm & Resources, Fuzhou 350002, Peoples R China
  • [ 3 ] [Lin, Chun-Xiang]Fuzhou Univ, Coll Environm & Resources, Fuzhou 350002, Peoples R China
  • [ 4 ] [Liu, Ming-Hua]Fuzhou Univ, Coll Environm & Resources, Fuzhou 350002, Peoples R China
  • [ 5 ] [Wei, Yu-Zhen]Fujian Gaoke Environm Protect Res Inst Co Ltd, Fuzhou 350002, Peoples R China
  • [ 6 ] [Lin, Chun-Xiang]Fujian Southeast Century Environm Protect Co Ltd, Fuzhou 350002, Peoples R China
  • [ 7 ] [Liu, Ming-Hua]Fujian Southeast Century Environm Protect Co Ltd, Fuzhou 350002, Peoples R China

Reprint 's Address:

  • 林春香

    [Lin, Chun-Xiang]Fuzhou Univ, Coll Environm & Resources, Fuzhou 350002, Peoples R China

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Source :

ASIAN JOURNAL OF CHEMISTRY

ISSN: 0970-7077

Year: 2014

Issue: 18

Volume: 26

Page: 6295-6298

0 . 3 5 5

JCR@2013

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 1

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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