A　layered　nanoarchitecture　composed　of　photoactive　MOFs　of　UiO-66-NH2　and　graphene　was　facilely　fabricated　herein　by　an　innovative　strategy,　which　utilizes　a　noncovalent　methodology　for　graphene　functionalization　combined　with　in　situ　self-assembling　and　a　solvothermal　synthesis　technique.　The　fabricated　hybrids　were　characterized　and　evaluated　in　detail　by　the　selective　photocatalytic　oxidation　of　benzyl　alcohol　under　visible　light.　The　hybrid　displayed　improved　efficiency　with　high　selectivity,　compared　with　the　parent　MOF.　The　characterization　results　clearly　demonstrate　that　this　originates　from　the　sandwich-like　hierarchical　nanoarchitecture　formed　by　the　compact　interaction　between　UiO-66-NH2　and　graphene　via　the　adopted　mediator.　The　synthesis　strategy　was　also　proven　effective　in　building　the　rGO/NH2-MIL-125(Ti)　hierarchical　nanoarchitecture.　Thus,　this　work　offers　a　general　strategy　for　constructing　MOF/graphene　sandwich　heterostructures,　which　have　great　potential　in　the　fields　of　electronics,　optics,　optoelectronics,　and　photoconversion.