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author:

Fang, Lihua (Fang, Lihua.) [1] | Zhang, Qi (Zhang, Qi.) [2] | Lin, Fen (Lin, Fen.) [3] | Tang, Dian (Tang, Dian.) [4] (Scholars:唐电) | Zhang, Teng (Zhang, Teng.) [5]

Indexed by:

EI Scopus SCIE

Abstract:

The insufficient thermal mechanical stability of sealing interface presents a challenge for the development of solid oxide fuel cells (SOFCs). Here we report for the first time that the presence of gadolinia-doped ceria (GDC) electrolyte leads to the formation of two hardystonite phases, (Ca(0.9)Z(0.03))(2)(Al0.63Zn0.37)(Si0.69Al0.31)(2)O-7 and Ca2ZnSi2O7, in the reaction couples between boroaluminosilicate sealing glass ceramics and GDC powders held at 700 degrees C for 30 days. Similarly, the aggregation of these two hardystonite phases also occurs at the interface between GDC and sealing glass ceramics under identical heat-treatment. In particular, (Ca(0.9)Z(0.03))(2)(Al0.63Zn0.37)(Si0.69Al0.31)(2)O-7 becomes the dominant phase at the sealing interface when the heat-treatment time increases from 7 days to 30 days. Moreover, the sealing interface remains intact after thermal cycles for 100 times, indicating the excellent thermal mechanical stability of hardystonite phases. Finally, the possible mechanism on the phase evolution of glass ceramic at the sealing interface has been proposed. (C) 2015 Elsevier Ltd. All rights reserved.

Keyword:

Gadolinia-doped ceria Phase evolution Sealing glass-ceramics Solid oxide fuel cells Thermal-mechanical stability

Community:

  • [ 1 ] [Fang, Lihua]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 2 ] [Zhang, Qi]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 3 ] [Lin, Fen]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 4 ] [Tang, Dian]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 5 ] [Zhang, Teng]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China

Reprint 's Address:

  • 张腾

    [Zhang, Teng]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China

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Source :

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY

ISSN: 0955-2219

Year: 2015

Issue: 7

Volume: 35

Page: 2201-2207

2 . 9 3 3

JCR@2015

5 . 8 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:335

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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