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Abstract：
A mild and straight-forward synthesis of alpha-trifluoroethoxy-substituted ketones from the trifluoroethoxylation of alpha-bromoketones with trifluoroethanol, under Cs2CO3-mediated conditions at room temperature, is described. The utility of this reaction for the synthesis of the trifluoroethoxy-substituted alcohols and pyrazoles is also showed. The reaction tolerates various functional groups and demonstrates efficient scalability and practicality. (C) 2015 Elsevier B.V. All rights reserved.
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JOURNAL OF FLUORINE CHEMISTRY
ISSN： 0022-1139
Year： 2015
Volume： 175
Page： 51-59
2 . 2 1 3
JCR@2015
1 . 7 0 0
JCR@2023
ESI Discipline： CHEMISTRY;
ESI HC Threshold：265
JCR Journal Grade：2
CAS Journal Grade：3
Cited Count：
WoS CC Cited Count： 8
SCOPUS Cited Count： 8
ESI Highly Cited Papers on the List： 0 Unfold All
WanFang Cited Count：
Chinese Cited Count：
30 Days PV： 2
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