• Complex
  • Title
  • Keyword
  • Abstract
  • Scholars
  • Journal
  • ISSN
  • Conference
成果搜索

author:

Li, Wenliang (Li, Wenliang.) [1] | Huang, Yiyin (Huang, Yiyin.) [2] | Tang, Dian (Tang, Dian.) [3] (Scholars:唐电) | Zhang, Teng (Zhang, Teng.) [4] | Wang, Yaobing (Wang, Yaobing.) [5]

Indexed by:

EI Scopus SCIE

Abstract:

In this paper, RuO2-5nO(2) binary oxides were prepared using a hydrothermal approach and added to Vulcan XC-72 carbon black as new support material for Pd. The X-ray diffraction, Transmission electron microscopy and X-ray photoelectronic spectra results show that the addition of binary oxides leads to the formation of (Ru,Sn)O-2 solid solution in Pd/C catalyst and reduces the particle size of Pd particles due to the anchoring effect. In addition, the electrochemical CO-striping measurement reveals that the Pd/RuO2-SnO2/C catalyst exhibits the largest electrochemical active surface and the best CO tolerance. Moreover, cyclic voltammetry and chronoamperometry tests demonstrate that the Pd/RuO2-5nO(2)/C catalyst possesses a much higher specific activity (4.4 mA cm(-2)) than that of the Pd/C catalyst (3.2 mA cm(-2)) towards ethylene glycol electrooxidation in alkaline media, and better stability as well. These results support the suitability of Pd/RuO2-SnO2/C catalyst developed in this work as a promising candidate for direct alcohol fuel cells (DAFCs) application. (C) 2015 Elsevier Ltd. All rights reserved.

Keyword:

Composite Support Direct Alcohol Fuel Cells Pd Catalysts Solid Solution

Community:

  • [ 1 ] [Li, Wenliang]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 2 ] [Tang, Dian]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 3 ] [Zhang, Teng]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 4 ] [Huang, Yiyin]Chinese Acad Sci, Fujian Prov Key Lab Nanomat, Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Peoples R China
  • [ 5 ] [Wang, Yaobing]Chinese Acad Sci, Fujian Prov Key Lab Nanomat, Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Peoples R China

Reprint 's Address:

  • 张腾

    [Zhang, Teng]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China

Show more details

Related Keywords:

Source :

ELECTROCHIMICA ACTA

ISSN: 0013-4686

Year: 2015

Volume: 174

Page: 178-184

4 . 8 0 3

JCR@2015

5 . 5 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:265

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

Online/Total:102/9987162
Address:FZU Library(No.2 Xuyuan Road, Fuzhou, Fujian, PRC Post Code:350116) Contact Us:0591-22865326
Copyright:FZU Library Technical Support:Beijing Aegean Software Co., Ltd. 闽ICP备05005463号-1