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author:

Liu, Xiaoju (Liu, Xiaoju.) [1] | Wang, Teng (Wang, Teng.) [2] | Li, Caicai (Li, Caicai.) [3] | Zheng, Zhenhuan (Zheng, Zhenhuan.) [4] (Scholars:郑振环) | Li, Qiang (Li, Qiang.) [5] (Scholars:李强)

Indexed by:

Scopus SCIE CSCD

Abstract:

The formation of thermally grown oxide (TGO) during high temperature is a key factor to the degradation of thermal barrier coatings (TBCs) applied on hot section components. In the present study both the CoNiCrAlY bond coat and ZrO2-8 wt.% Y2O3 (8YSZ) ceramic coat of TBCs were prepared by air plasma spraying (APS). The composition and microstructure of TGO in TBCs were investigated using scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS) and X-ray diffraction (XRD) analysis. The growth rate of TGO for TBC and pure BC were gained after isothermal oxidation at 1100 degrees C for various times. The results showed that as-sprayed bond coat consisted of beta and gamma/gamma'phases, beta phase reducesd as the oxidation time increased. The TGO comprised alpha-Al2O3 formed in the first 2 h. CoO, NiO, Cr2O3 and spinel oxides appeared after 20 h of oxidation. Contents of CoO and NiO reduced while that of Cr2O3 and spinel oxides increased in the later oxidation stage. The TGO eventually consisted of a sub-Al2O3 layer with columnar microstructure and the upper porous CS clusters. The TGO growth kinetics for two kinds of samples followed parabolic laws, with oxidation rate constant of 0.344 mu m/h(0.5) for TBCs and 0.354 mu m/h(0.5) for pure BCs. (C) 2016 The Authors. Production and hosting by Elsevier B.V. on behalf of Chinese Materials Research Society. This is an open access article under the CC BY-NC-ND license (hap://creativecommons.org/licen,,eqb-tic-nd/4.0/).

Keyword:

Air plasma spraying (APS) CoNiCrA1Y Isothermal oxidation Oxidation rate Thermal bather coatings (TBCs) YSZ ceramic coat

Community:

  • [ 1 ] [Liu, Xiaoju]Fuzhou Univ, Sch Mat Sci & Engn, Fuzhou 350116, Peoples R China
  • [ 2 ] [Wang, Teng]Fuzhou Univ, Sch Mat Sci & Engn, Fuzhou 350116, Peoples R China
  • [ 3 ] [Li, Caicai]Fuzhou Univ, Sch Mat Sci & Engn, Fuzhou 350116, Peoples R China
  • [ 4 ] [Zheng, Zhenhuan]Fuzhou Univ, Sch Mat Sci & Engn, Fuzhou 350116, Peoples R China
  • [ 5 ] [Li, Qiang]Fuzhou Univ, Sch Mat Sci & Engn, Fuzhou 350116, Peoples R China

Reprint 's Address:

  • 李强

    [Li, Qiang]Fuzhou Univ, Sch Mat Sci & Engn, Fuzhou 350116, Peoples R China

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Source :

PROGRESS IN NATURAL SCIENCE-MATERIALS INTERNATIONAL

ISSN: 1002-0071

CN: 10-1147/N

Year: 2016

Issue: 1

Volume: 26

Page: 103-111

2 . 0 3 8

JCR@2016

4 . 8 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:324

JCR Journal Grade:2

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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