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author:

Liu, X. (Liu, X..) [1] | Wang, T. (Wang, T..) [2] | Li, C. (Li, C..) [3] | Zheng, Z. (Zheng, Z..) [4] | Li, Q. (Li, Q..) [5]

Indexed by:

Scopus CSCD

Abstract:

The formation of thermally grown oxide (TGO) during high temperature is a key factor to the degradation of thermal barrier coatings (TBCs) applied on hot section components. In the present study both the CoNiCrAlY bond coat and ZrO2-8 wt.% Y2O3 (8YSZ) ceramic coat of TBCs were prepared by air plasma spraying (APS). The composition and microstructure of TGO in TBCs were investigated using scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS) and X-ray diffraction (XRD) analysis. The growth rate of TGO for TBC and pure BC were gained after isothermal oxidation at 1100 °C for various times. The results showed that as-sprayed bond coat consisted of β and γ/γ'phases, β phase reducesd as the oxidation time increased. The TGO comprised α-Al2O3 formed in the first 2 h. CoO, NiO, Cr2O3 and spinel oxides appeared after 20 h of oxidation. Contents of CoO and NiO reduced while that of Cr2O3 and spinel oxides increased in the later oxidation stage. The TGO eventually consisted of a sub-Al2O3 layer with columnar microstructure and the upper porous CS clusters. The TGO growth kinetics for two kinds of samples followed parabolic laws, with oxidation rate constant of 0.344 μm/h0.5 for TBCs and 0.354 μm/h0.5 for pure BCs. © 2016 The Authors.

Keyword:

Air plasma spraying (APS); CoNiCrAlY; Isothermal oxidation; Oxidation rate; Thermal barrier coatings (TBCs); YSZ ceramic coat

Community:

  • [ 1 ] [Liu, X.]School of Materials Science and Engineering, Fuzhou University, Fuzhou, 350116, China
  • [ 2 ] [Wang, T.]School of Materials Science and Engineering, Fuzhou University, Fuzhou, 350116, China
  • [ 3 ] [Li, C.]School of Materials Science and Engineering, Fuzhou University, Fuzhou, 350116, China
  • [ 4 ] [Zheng, Z.]School of Materials Science and Engineering, Fuzhou University, Fuzhou, 350116, China
  • [ 5 ] [Li, Q.]School of Materials Science and Engineering, Fuzhou University, Fuzhou, 350116, China

Reprint 's Address:

  • [Li, Q.]School of Materials Science and Engineering, Fuzhou UniversityChina

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Source :

Progress in Natural Science: Materials International

ISSN: 1002-0071

Year: 2016

Issue: 1

Volume: 26

Page: 103-111

2 . 0 3 8

JCR@2016

4 . 8 0 0

JCR@2023

ESI HC Threshold:324

JCR Journal Grade:2

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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