Two　new　organometallic　copolymers　(PVFVM1　and　PVFVM1-1)　bearing　different　molar　ratios　of　ferrocene　and　triphenylamine　pendants　were　successfully　designed　and　synthesized　as　cathode　active　materials　for　organic-battery　applications.　Their　structural　and　thermal　characteristics　were　determined　by　H-1　NMR　spectroscopy,　Fourier　transform　infrared　(FTIR)　spectroscopy,　size　exclusion　chromatography　(SEC),　and　thermogravimetric　analysis　(TGA).　Cyclic　voltammograms　of　the　as-prepared　polymers　show　that　the　electrochemical　reactions　of　the　ferrocene　and　triphenylamine　moieties　are　reversible　after　the　first　cycle.　A　composite　electrode　based　on　copolymer　PVFVM1　exhibits　an　initial　specific　discharge　capacity　of　102　mAhg(-1),　which　corresponds　to　98%　of　its　theoretical　capacity　(104　mAhg(-1)).　The　cycle　endurances　for　both　polymers　have　been　evaluated　for　over　50　cycles.　Our　results　show　that　both　copolymers　are　good　candidates　as　a　new　class　of　cathode　active　materials　and　charge-storage　materials　for　rechargeable　batteries.