Cluster Organic Frameworks Constructed from Heterometallic Supertetrahedral Cluster Secondary Building Units - Details

author：

Lin, L.-D. (Lin, L.-D..) ^[1] | Li, X.-X. (Li, X.-X..) ^[2] | Qi, Y.-J. (Qi, Y.-J..) ^[3] | Ma, X. (Ma, X..) ^[4] | Zheng, S.-T. (Zheng, S.-T..) ^[5]

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Abstract：

The　two　novel　cluster　organic　frameworks　based　on　heterometallic　supertetrahedral　cluster　secondary　building　units　(SBUs)　[Cd　4　Cu　6　(L)　4　(Ac)　7　(H　2　O)　4　](Ac)·7H　2　O　(1)　and　[Mn　4　Cu　6　(L)　4　(Ac)　4.5　(H　2　O)　9　]CuCN(Ac)　3.5　·H　2　O　(2),　where　H　3　L　=　2-(hydroxymethyl)-2-(pyridin-4-yl)-1,3-propanediol　and　Ac　=　CH　3　COO　-　,　have　been　prepared　under　solvothermal　conditions.　1　and　2　are　the　first　cases　of　cluster　organic　frameworks　containing　Cd-Cu/Mn-Cu　heterometallic　supertetrahedral　cluster　SBUs.　Furthermore,　1　and　2　show　an　integration　of　magnetic　properties　and　adsorption　properties　from　both　the　heterometallic　cluster　secondary　building　units　and　the　framework　in　a　porous　material.　©　2017　American　Chemical　Society.

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[ 1 ] [Lin, L.-D.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian, 350108, China
[ 2 ] [Li, X.-X.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian, 350108, China
[ 3 ] [Li, X.-X.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350108, China
[ 4 ] [Qi, Y.-J.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian, 350108, China
[ 5 ] [Ma, X.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian, 350108, China
[ 6 ] [Zheng, S.-T.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian, 350108, China
[ 7 ] [Zheng, S.-T.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350108, China

Reprint 's Address：

[Li, X.-X.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou UniversityChina

Email：

lxx@fzu.edu.cn

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Source ：

Inorganic Chemistry

ISSN： 0020-1669

Year： 2017

Issue： 8

Volume： 56

Page： 4635-4642

4 . 7

JCR@2017

4 . 3 0 0

JCR@2023

ESI HC Threshold：226

JCR Journal Grade：1

CAS Journal Grade：1

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ESI Highly Cited Papers on the List： 0 Unfold All

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