AgCu(IO3)(3): Synthesis, Crystal Structure and Magnetic Property - Details

author：

Wang Wen-Wen (Wang Wen-Wen.) ^[1] | Ruan Ting-Ting (Ruan Ting-Ting.) ^[2] | Xu Xiang (Xu Xiang.) ^[3] | Mao Jiang-Gao (Mao Jiang-Gao.) ^[4]

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Scopus SCIE CSCD

Abstract：

A　new　mixed　metal　iodate,　namely　AgCu(IO3)(3),　has　been　prepared　using　hydrothermal　method.　AgCu(IO3)(3)　crystallizes　in　the　triclinic　group　P　(1)　over　bar　with　a　=　7.3063(6),　b　=　7.8050(6),　c　=　8.2447(6)　angstrom,　alpha　=　67.212(7),　beta　=　74.978(7),　gamma　=　80.972(7)degrees,　V　=　417.80(6)　angstrom(3)　and　Z　=　2.　The　structure　features　one-dimensional　[Cu(IO3)(3)](n)(n-)　anionic　chains　that　are　separated　by　Ag+　cations.　Such　[Cu(IO3)(3)](n)(n-)　chain　is　composed　of　[Cu2O11](n)　chain　decorated　by　unidentate　hanging　and　bidentate　bridging　iodate　groups.　Thermal　study　implies　that　AgCu(IO3)(3)　is　thermally　stable　up　to　460　degrees　C　and　the　optical　measurement　determined　the　optical　band　gap　of　3.11　eV　with　a　broad　absorption　band　centered　at　765　nm.　Magnetic　investigations　show　that　AgCu(IO3)(3)　is　a　soft　ferromagnet.

Keyword：

crystal structure hydrothermal synthesis magnetic property metal iodate

Community：

[ 1 ] [Wang Wen-Wen]Fuzhou Univ, Coll Chem, Fuzhou 350108, Fujian, Peoples R China
[ 2 ] [Ruan Ting-Ting]Fuzhou Univ, Coll Chem, Fuzhou 350108, Fujian, Peoples R China
[ 3 ] [Wang Wen-Wen]Chinese Acad Sci, State Key Lab Struct Chem, Fujian Inst Res Struct Matter, Fuzhou 350002, Fujian, Peoples R China
[ 4 ] [Ruan Ting-Ting]Chinese Acad Sci, State Key Lab Struct Chem, Fujian Inst Res Struct Matter, Fuzhou 350002, Fujian, Peoples R China
[ 5 ] [Xu Xiang]Chinese Acad Sci, State Key Lab Struct Chem, Fujian Inst Res Struct Matter, Fuzhou 350002, Fujian, Peoples R China
[ 6 ] [Mao Jiang-Gao]Chinese Acad Sci, State Key Lab Struct Chem, Fujian Inst Res Struct Matter, Fuzhou 350002, Fujian, Peoples R China

Reprint 's Address：

[Xu Xiang]Chinese Acad Sci, State Key Lab Struct Chem, Fujian Inst Res Struct Matter, Fuzhou 350002, Fujian, Peoples R China;;[Mao Jiang-Gao]Chinese Acad Sci, State Key Lab Struct Chem, Fujian Inst Res Struct Matter, Fuzhou 350002, Fujian, Peoples R China

Email：

xiangxu@fjirsm.ac.cn |
mjg@fjirsm.ac.cn

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Version：

AgCu(IO3)3: Synthesis, crystal structure and magnetic property
2017，Jiegou Huaxue

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Source ：

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY

ISSN： 0254-5861

CN： 35-1112/TQ

Year： 2017

Issue： 9

Volume： 36

Page： 1456-1464

0 . 6 5 9

JCR@2017

5 . 9 0 0

JCR@2023

ESI Discipline： CHEMISTRY;

ESI HC Threshold：226

JCR Journal Grade：4

CAS Journal Grade：4

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SCOPUS Cited Count：

ESI Highly Cited Papers on the List： 0 Unfold All

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Chinese Cited Count：

30 Days PV： 1

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