AgCu(IO3)3: Synthesis, crystal structure and magnetic property - Details

author：

Wang, W.-W. (Wang, W.-W..) ^[1] | Ruan, T.-T. (Ruan, T.-T..) ^[2] | Xu, X. (Xu, X..) ^[3] | Mao, J.-G. (Mao, J.-G..) ^[4]

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Abstract：

A　new　mixed　metal　iodate,　namely　AgCu(IO3)3,　has　been　prepared　using　hydrothermal　method.　AgCu(IO3)3　crystallizes　in　the　triclinic　group　P1-　with　a　=　7.3063(6),　b　=　7.8050(6),　c　=　8.2447(6)　Å,　α　=　67.212(7),　β　=　74.978(7),　γ　=　80.972(7)o,　V　=　417.80(6)　Å3　and　Z　=　2.　The　structure　features　one-dimensional　[Cu(IO3)3]n　n-　anionic　chains　that　are　separated　by　Ag+　cations.　Such　[Cu(IO3)3]n　n-　chain　is　composed　of　[Cu2O11]n　chain　decorated　by　unidentate　hanging　and　bidentate　bridging　iodate　groups.　Thermal　study　implies　that　AgCu(IO3)3　is　thermally　stable　up　to　460　oC　and　the　optical　measurement　determined　the　optical　band　gap　of　3.11　eV　with　a　broad　absorption　band　centered　at　765　nm.　Magnetic　investigations　show　that　AgCu(IO3)3　is　a　soft　ferromagnet.

Keyword：

Crystal structure; Hydrothermal synthesis; Magnetic property; Metal iodate

Community：

[ 1 ] [Wang, W.-W.]College of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 2 ] [Wang, W.-W.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
[ 3 ] [Ruan, T.-T.]College of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 4 ] [Ruan, T.-T.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
[ 5 ] [Xu, X.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
[ 6 ] [Mao, J.-G.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China

Reprint 's Address：

[Xu, X.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of SciencesChina

Email：

xiangxu@fjirsm.ac.cn

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Source ：

Jiegou Huaxue

ISSN： 0254-5861

CN： 35-1112/TQ

Year： 2017

Issue： 9

Volume： 36

Page： 1456-1464

0 . 6 5 9

JCR@2017

5 . 9 0 0

JCR@2023

ESI HC Threshold：226

JCR Journal Grade：4

CAS Journal Grade：4

Cited Count：

WoS CC Cited Count： 0

SCOPUS Cited Count： 1

ESI Highly Cited Papers on the List： 0 Unfold All

WanFang Cited Count：

Chinese Cited Count：

30 Days PV： 0

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