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author:

Hong, Zhensheng (Hong, Zhensheng.) [1] | Kang, Meiling (Kang, Meiling.) [2] | Chen, Xiaohui (Chen, Xiaohui.) [3] | Zhou, Kaiqiang (Zhou, Kaiqiang.) [4] | Huang, Zhigao (Huang, Zhigao.) [5] | Wei, Mingdeng (Wei, Mingdeng.) [6] (Scholars:魏明灯)

Indexed by:

EI Scopus SCIE

Abstract:

TiO2 is a most promising anode candidate for rechargeable Na-ion batteries (NIBs) because of its appropriate working voltage, low cost, and superior structural stability during chage/discharge process. Nevertheless, it suffers from intrinsically low electrical conductivity. Herein, we report an in situ synthesis of Co2+-doped TiO2 through the thermal treatment of metal organic frameworks precursors of MIL-125(Ti)-Co as a superior anode material for NIBs. The Co2+-doped TiO2 possesses uniform nanodisk morphology, a large surface area and mesoporous structure with narrow pore distribution. The reversible capacity, Coulombic efficiency (CE) and rate capability can be improved by Co2+ doping in mesoporous TiO2 anode. Co2+-doped mesoporous TiO2 nanodisks exhibited a high reversible capacity of 232 mAhg(-1) at 0.1 Ag1-, good rate capability and cycling stability with a stable capacity of about 140 mAhg(-1) at 0.5 Ag1- after 500 cycles. The enhanced Na-ion storage performance could be due to the increased electrical conductivity revealed by Kelvin probe force microscopy measurements.

Keyword:

anode Co2+ doping MOP sodium-ion batteries TiO2

Community:

  • [ 1 ] [Hong, Zhensheng]Fujian Normal Univ, Coll Phys & Energy, Fujian Prov Key Lab Quantum Manipulat & New Energ, Fuzhou 350117, Fujian, Peoples R China
  • [ 2 ] [Kang, Meiling]Fujian Normal Univ, Coll Phys & Energy, Fujian Prov Key Lab Quantum Manipulat & New Energ, Fuzhou 350117, Fujian, Peoples R China
  • [ 3 ] [Chen, Xiaohui]Fujian Normal Univ, Coll Phys & Energy, Fujian Prov Key Lab Quantum Manipulat & New Energ, Fuzhou 350117, Fujian, Peoples R China
  • [ 4 ] [Zhou, Kaiqiang]Fujian Normal Univ, Coll Phys & Energy, Fujian Prov Key Lab Quantum Manipulat & New Energ, Fuzhou 350117, Fujian, Peoples R China
  • [ 5 ] [Huang, Zhigao]Fujian Normal Univ, Coll Phys & Energy, Fujian Prov Key Lab Quantum Manipulat & New Energ, Fuzhou 350117, Fujian, Peoples R China
  • [ 6 ] [Hong, Zhensheng]Fujian Prov Collaborat Innovat Ctr Optoelect Semi, Xiamen 361005, Peoples R China
  • [ 7 ] [Huang, Zhigao]Fujian Prov Collaborat Innovat Ctr Optoelect Semi, Xiamen 361005, Peoples R China
  • [ 8 ] [Hong, Zhensheng]Fuzhou Univ, Inst Adv Energy Mat, Fuzhou 350002, Fujian, Peoples R China
  • [ 9 ] [Kang, Meiling]Fuzhou Univ, Inst Adv Energy Mat, Fuzhou 350002, Fujian, Peoples R China
  • [ 10 ] [Wei, Mingdeng]Fuzhou Univ, Inst Adv Energy Mat, Fuzhou 350002, Fujian, Peoples R China

Reprint 's Address:

  • 洪振生

    [Hong, Zhensheng]Fujian Normal Univ, Coll Phys & Energy, Fujian Prov Key Lab Quantum Manipulat & New Energ, Fuzhou 350117, Fujian, Peoples R China;;[Hong, Zhensheng]Fujian Prov Collaborat Innovat Ctr Optoelect Semi, Xiamen 361005, Peoples R China;;[Hong, Zhensheng]Fuzhou Univ, Inst Adv Energy Mat, Fuzhou 350002, Fujian, Peoples R China

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Source :

ACS APPLIED MATERIALS & INTERFACES

ISSN: 1944-8244

Year: 2017

Issue: 37

Volume: 9

Page: 32071-32079

8 . 0 9 7

JCR@2017

8 . 5 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:306

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 60

SCOPUS Cited Count: 63

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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