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[期刊论文]

In situ fabrication of cellular architecture on silver metals using methane/oxygen gas mixture and its application for energy storage

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author:

Cao, Fenghui (Cao, Fenghui.) [1] | Wang, Zhihong (Wang, Zhihong.) [2] | Wang, Yuzhi (Wang, Yuzhi.) [3] | Unfold

Indexed by:

EI Scopus SCIE

Abstract:

Cellular metals with a large surface-to-volume ratio and excellent electrical conductivity have attracted great attention due to their wide application. However, the existing processes for fabrication of cellular metallic structures are generally complex and dependent on the sacrificial materials or templates, and therefore, it is highly desirable to develop a facile process. Herein, we propose a novel gas-assisted reconstruction strategy for in situ fabrication of micron-porous architectures on Ag precursor metal using a CH4/O-2 gas mixture at 750 degrees C. The obtained results indicate that large-area and clean, porous Ag architectures are successfully created through the treatment in CH4/O2 gas. The formation of cellular structure is mainly due to the simultaneous diffusion of H-2, CO and O-2 into Ag bulk and fast reaction at elevated temperatures. The process is clean and applicable to creation of porous architectures (from surface texturing to 3-D cellular structure) on Ag metal, avoiding the use of sacrificial materials or templates. Furthermore, we have demonstrated that the formed micron-porous Ag sheet with large effective area, high electrical conductivity can be directly used as a free-standing electrode for electrochemical supercapacitors with a high capacitance. (C) 2018 Elsevier Ltd. All rights reserved.

Keyword:

Cellular structure CH4/O-2 mixture Silver metal Supercapacitor

Community:

  • [ 1 ] [Cao, Fenghui]Daqing Normal Univ, Sch Mechatron Engn, Daqing 163712, Heilongjiang, Peoples R China
  • [ 2 ] [Cao, Fenghui]Harbin Inst Technol, Dept Phys, Yikuang St 2, Harbin 150001, Heilongjiang, Peoples R China
  • [ 3 ] [Wang, Zhihong]Harbin Inst Technol, Dept Phys, Yikuang St 2, Harbin 150001, Heilongjiang, Peoples R China
  • [ 4 ] [Wang, Yuzhi]Harbin Inst Technol, Dept Phys, Yikuang St 2, Harbin 150001, Heilongjiang, Peoples R China
  • [ 5 ] [Yan, Yingming]Harbin Inst Technol, Dept Phys, Yikuang St 2, Harbin 150001, Heilongjiang, Peoples R China
  • [ 6 ] [Liu, Mengting]Harbin Inst Technol, Dept Phys, Yikuang St 2, Harbin 150001, Heilongjiang, Peoples R China
  • [ 7 ] [Li, Lang]Harbin Inst Technol, Dept Phys, Yikuang St 2, Harbin 150001, Heilongjiang, Peoples R China
  • [ 8 ] [Lv, Zhe]Harbin Inst Technol, Dept Phys, Yikuang St 2, Harbin 150001, Heilongjiang, Peoples R China
  • [ 9 ] [Ao, Guanghong]Harbin Univ Sci & Technol, Dept Phys, Harbin 150080, Heilongjiang, Peoples R China
  • [ 10 ] [Chen, Kongfa]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China

Reprint 's Address:

  • 陈孔发

    [Wang, Zhihong]Harbin Inst Technol, Dept Phys, Yikuang St 2, Harbin 150001, Heilongjiang, Peoples R China;;[Chen, Kongfa]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China

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Source :

ELECTROCHIMICA ACTA

ISSN: 0013-4686

Year: 2018

Volume: 280

Page: 25-32

5 . 3 8 3

JCR@2018

5 . 5 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:209

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 5

30 Days PV: 0

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