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author:

Cao, F. (Cao, F..) [1] | Wang, Z. (Wang, Z..) [2] | Wang, Y. (Wang, Y..) [3] | Yan, Y. (Yan, Y..) [4] | Liu, M. (Liu, M..) [5] | Li, L. (Li, L..) [6] | Ao, G. (Ao, G..) [7] | Chen, K. (Chen, K..) [8] | Lv, Z. (Lv, Z..) [9]

Indexed by:

Scopus

Abstract:

Cellular metals with a large surface-to-volume ratio and excellent electrical conductivity have attracted great attention due to their wide application. However, the existing processes for fabrication of cellular metallic structures are generally complex and dependent on the sacrificial materials or templates, and therefore, it is highly desirable to develop a facile process. Herein, we propose a novel gas-assisted reconstruction strategy for in situ fabrication of micron-porous architectures on Ag precursor metal using a CH 4 /O 2 gas mixture at 750 °C. The obtained results indicate that large-area and clean, porous Ag architectures are successfully created through the treatment in CH 4 /O 2 gas. The formation of cellular structure is mainly due to the simultaneous diffusion of H 2 , CO and O 2 into Ag bulk and fast reaction at elevated temperatures. The process is clean and applicable to creation of porous architectures (from surface texturing to 3-D cellular structure) on Ag metal, avoiding the use of sacrificial materials or templates. Furthermore, we have demonstrated that the formed micron-porous Ag sheet with large effective area, high electrical conductivity can be directly used as a free-standing electrode for electrochemical supercapacitors with a high capacitance. © 2018 Elsevier Ltd

Keyword:

Cellular structure; CH 4 /O 2 mixture; Silver metal; Supercapacitor

Community:

  • [ 1 ] [Cao, F.]School of Mechatronic Engineering, Daqing Normal University, Daqing, Heilongjiang 163712, China
  • [ 2 ] [Cao, F.]Department of Physics, Harbin Institute of Technology, Yikuang Street 2#, Harbin, Heilongjiang 150001, China
  • [ 3 ] [Wang, Z.]Department of Physics, Harbin Institute of Technology, Yikuang Street 2#, Harbin, Heilongjiang 150001, China
  • [ 4 ] [Wang, Y.]Department of Physics, Harbin Institute of Technology, Yikuang Street 2#, Harbin, Heilongjiang 150001, China
  • [ 5 ] [Yan, Y.]Department of Physics, Harbin Institute of Technology, Yikuang Street 2#, Harbin, Heilongjiang 150001, China
  • [ 6 ] [Liu, M.]Department of Physics, Harbin Institute of Technology, Yikuang Street 2#, Harbin, Heilongjiang 150001, China
  • [ 7 ] [Li, L.]Department of Physics, Harbin Institute of Technology, Yikuang Street 2#, Harbin, Heilongjiang 150001, China
  • [ 8 ] [Ao, G.]Department of Physics, Harbin University of Science and Technology, Heilongjiang, 150080, China
  • [ 9 ] [Chen, K.]College of Materials Science and Engineering, Fuzhou University, Fuzhou, Fujian 350108, China
  • [ 10 ] [Lv, Z.]Department of Physics, Harbin Institute of Technology, Yikuang Street 2#, Harbin, Heilongjiang 150001, China

Reprint 's Address:

  • [Wang, Z.]Department of Physics, Harbin Institute of Technology, Yikuang Street 2#, China

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Source :

Electrochimica Acta

ISSN: 0013-4686

Year: 2018

Volume: 280

Page: 25-32

5 . 3 8 3

JCR@2018

5 . 5 0 0

JCR@2023

ESI HC Threshold:209

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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