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author:

He, Zelong (He, Zelong.) [1] | Zhang, Lan (Zhang, Lan.) [2] (Scholars:张兰) | He, Shuai (He, Shuai.) [3] | Ai, Na (Ai, Na.) [4] (Scholars:艾娜) | Chen, Kongfa (Chen, Kongfa.) [5] (Scholars:陈孔发) | Shao, Yanqun (Shao, Yanqun.) [6] (Scholars:邵艳群) | Jiang, San Ping (Jiang, San Ping.) [7]

Indexed by:

Scopus SCIE

Abstract:

Reversing the direction of polarization current is essential for reversible solid oxide cells technologies, but its effect on cobaltite based perovskite oxygen electrodes is largely unknown. Herein, we report the operating stability and microstructure at the electrode/electrolyte interface of La0.57Sr0.38Co0.18Fe0.72Nb0.1O3-delta (LSCFN) oxygen electrodes assembled on barrier-layer-free Y2O3-ZrO2 electrolyte under cyclic anodic/cathodic polarization mode at 0.5 A cm(-2) and 750 degrees C. During the cyclic polarization, the electrocatalytic activity of LSCFN electrode is drastically deteriorated in cathodic mode, but the performance loss is largely recoverable in anodic mode. This is due to the fact that the surface segregation of Sr and accumulation at the electrode/electrolyte interface by cathodic polarization can be remarkably mitigated by anodic polarization. The time period in each cycle plays a key role in determining the accumulation of Sr species at the electrode/electrolyte interface. A full cell operating in a time period of 12 h fuel-cell/12 h electrolysis is reversible for a duration of 240 h, in contrast to the performance degradation in a shorter time period of 4 h fuel cell/4 h electrolysis. The present study sheds lights on applying cobaltite based perovskite oxygen electrodes on barrier-layer-free YSZ electrolyte for reliable solid oxide cells.

Keyword:

Cyclic polarization LSCFN oxygen electrode Performance recovery Reversible solid oxide cells Sr surface segregation

Community:

  • [ 1 ] [He, Zelong]Yangtze Normal Univ, Sch Elect & Informat Engn, Chongqing 408100, Peoples R China
  • [ 2 ] [Zhang, Lan]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 3 ] [Chen, Kongfa]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 4 ] [Shao, Yanqun]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 5 ] [Zhang, Lan]Nanyang Technol Univ, Energy Res Inst, Singapore 637553, Singapore
  • [ 6 ] [He, Shuai]Curtin Univ, Fuels & Energy Technol Inst, Perth, WA 6102, Australia
  • [ 7 ] [Jiang, San Ping]Curtin Univ, Fuels & Energy Technol Inst, Perth, WA 6102, Australia
  • [ 8 ] [He, Shuai]Curtin Univ, Deparonent Chem Engn, Perth, WA 6102, Australia
  • [ 9 ] [Jiang, San Ping]Curtin Univ, Deparonent Chem Engn, Perth, WA 6102, Australia
  • [ 10 ] [Ai, Na]Fuzhou Univ, Testing Ctr, Fuzhou 350108, Fujian, Peoples R China

Reprint 's Address:

  • 陈孔发 邵艳群

    [Chen, Kongfa]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China;;[Shao, Yanqun]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China;;[Jiang, San Ping]Curtin Univ, Fuels & Energy Technol Inst, Perth, WA 6102, Australia;;[Jiang, San Ping]Curtin Univ, Deparonent Chem Engn, Perth, WA 6102, Australia

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Source :

JOURNAL OF POWER SOURCES

ISSN: 0378-7753

Year: 2018

Volume: 404

Page: 73-80

7 . 4 6 7

JCR@2018

8 . 1 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:284

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 19

SCOPUS Cited Count: 24

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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